Red Algae-Derived Carrageenan Coatings for Marine Antifouling Applications

We report a facile approach for the fabrication of a marine antifouling coating using the red algae-derived polysaccharide, carrageenan (CAR). Because CAR is hydrophilic and negatively charged, we hypothesized that it would form strong hydration layers upon adsorption onto solid surfaces, thereby ex...

Full description

Saved in:
Bibliographic Details
Published in:Biomacromolecules 2020-12, Vol.21 (12), p.5086-5092
Main Authors: Kim, Dahee, Kang, Sung Min
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We report a facile approach for the fabrication of a marine antifouling coating using the red algae-derived polysaccharide, carrageenan (CAR). Because CAR is hydrophilic and negatively charged, we hypothesized that it would form strong hydration layers upon adsorption onto solid surfaces, thereby exhibiting marine antifouling properties. Although various types of CAR can be used for marine antifouling, a universally applicable coating method has not yet been developed; thus, a systematic study on the marine antifouling property of CAR coating is lacking. Here, we fabricated a versatile CAR coating via ZrIV-mediated multiple cross-linking reactions between the sulfate groups of CAR and metal ions and successfully deposited κ-, ι-, and λ-CAR onto solid surfaces. Specifically, λ-CAR showed superior marine antifouling performance, as evidenced by the results of the marine diatom adhesion assays.
ISSN:1525-7797
1526-4602
DOI:10.1021/acs.biomac.0c01248