Mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes

Rhodium-catalyzed alkenylation of allylbenzene derivatives via C-C bond activation provides an unprecedented access to alkenylation products with remarkable regioselectivities. Using DFT calculations, we elucidate the reaction mechanism and the origins of the regioselectivity. The mechanism and orig...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2020-12, Vol.49 (47), p.17395-174
Main Authors: Li, Tian-Qi, Tan, Jing-Yi, Deng, Wei, Xu, Zheng-Yang
Format: Article
Language:English
Subjects:
Catalysis
Covalent bonds
Origins
Reaction mechanisms
Regioselectivity
Rhodium
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Summary:Rhodium-catalyzed alkenylation of allylbenzene derivatives via C-C bond activation provides an unprecedented access to alkenylation products with remarkable regioselectivities. Using DFT calculations, we elucidate the reaction mechanism and the origins of the regioselectivity. The mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes.
ISSN:1477-9226
1477-9234
DOI:10.1039/d0dt03704d