Electrospun Wrinkled Porous Polyimide Nanofiber-Based Filter via Thermally Induced Phase Separation for Efficient High-Temperature PMs Capture

• Published in: ACS applied materials & interfaces 2020-12, Vol.12 (50), p.56499-56508
• Main Authors: Xie, Fan, Wang, Yafang, Zhuo, Longhai, Jia, Fengfeng, Ning, Doudou, Lu, Zhaoqing
• Format: Article
• Language: English
• Subjects: Applications of Polymer, Composite, and Coating Materials
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.0c18143

Benefiting from its superior thermal stability, polyimide (PI) fiber-based composites have attracted wide attention in the field of high-temperature filtration and separation. However, the trade-off between filtration efficiency and pressure drop of traditional PI filters with single morphology and structure still remains challenging. Herein, the electrospun PI high-temperature-resistant air filter was fabricated via thermal-induced phase separation (TIPS), employing polyacrylonitrile (PAN) as a template. The PI nanofibers exhibited special wrinkled porous structure, and the filter possessed a high specific surface area of 304.77 m2/g. The removal of PAN changed the chemical composition of the fiber and induced PI molecules to form complex folds on the surface of the fiber, thus forming the wrinkled porous structure. Additionally, the wrinkled porous PI nanofiber filter displayed a high PM0.3 removal efficiency of 99.99% with a low pressure drop of 43.35 Pa at room temperature, and the filtration efficiency was still over 97% after being used for long time. Moreover, the efficiency of the filter could even reach 95.55% at a high temperature of 280 °C. The excellent filtration performance was attributed to the special wrinkled porous surface, which could limit the Brownian motion of PMs and reinforce the mechanical interception effect to capture the particulate matters (PMs) on the surface of the filter. Therefore, this work provided a novel strategy for the fabrication of filters with special morphology to cope with increasingly serious air pollution in the industrial field.