The Study of the Low-Lying Valence-Shell Excitations of Hydrogen Sulfide by Fast Electron Impact

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2020-12, Vol.124 (52), p.10997-11005
• Main Authors: Wang, Li-Han, Du, Xiao-Jiao, Xu, Yuan-Chen, Li, Tian-Jun, Ma, Zi-Ru, Wang, Shu-Xing, Zhu, Lin-Fan
• Format: Article
• Language: English
• Subjects: A: Kinetics, Dynamics, Photochemistry, and Excited States
• ISSN: 1089-5639; 1520-5215
• DOI: 10.1021/acs.jpca.0c09480

The valence-shell excitations of hydrogen sulfide have been studied by fast electron impact at a collision energy of 1.5 keV and an energy resolution of about 70 meV. By analyzing the variations of intensity and shape of the feature in the range of 5.0–7.5 eV at different scattering angles, the excitation energy of 5.85 ± 0.01 eV and the line width of 0.80 ± 0.01 eV of the 3b2 1A2 state have been determined. The generalized oscillator strengths of the valence-shell excitations in the energy range of 5.0–9.2 eV of hydrogen sulfide have been determined from the measured spectra. The corresponding optical oscillator strengths have been obtained by extrapolating the generalized oscillator strengths to the limit of zero squared momentum transfer. The integral cross sections have also been systematically determined from the threshold to 5000 eV by means of the BE-scaling method. The presently obtained oscillator strengths and integral cross sections have significant applications in the studies of planetary atmospheres and interstellar gases.