Environmentally benign approach towards C–S cross-coupling reaction by organo-copper(II) complex

C–S cross-coupling reaction in water giving an excellent yield of the desired C–S coupled product by using a newly developed Bis[2-(4,5-diphenyl-1 H -imidazol-2-yl)-4-nitrophenolato] copper(II) dehydrate complex as catalyst. Although it was the first report of the synthesis of such a novel organo-co...

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Bibliographic Details
Published in:Molecular diversity 2022-02, Vol.26 (1), p.505-511
Main Authors: Singha, Rabindranath, Chettri, Sailesh, Brahman, Dhiraj, Sinha, Biswajit, Ghosh, Pranab
Format: Article
Language:English
Subjects:
Biochemistry
Biomedical and Life Sciences
Catalysis
Chromatography
Copper
Laboratories
Life Sciences
Optimization
Organic Chemistry
Pharmacy
Polymer Sciences
Short Communication
Solvents
Water
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Summary:C–S cross-coupling reaction in water giving an excellent yield of the desired C–S coupled product by using a newly developed Bis[2-(4,5-diphenyl-1 H -imidazol-2-yl)-4-nitrophenolato] copper(II) dehydrate complex as catalyst. Although it was the first report of the synthesis of such a novel organo-copper complex from our laboratory, its potential catalytic application was not tested so far. Keeping this in mind and based on our anticipation, we developed a greener route for the C–S coupling reaction. The result is very interesting and comprises the subject matter of this report. Graphic abstract
ISSN:1381-1991
1573-501X
DOI:10.1007/s11030-020-10180-5