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THE EXTRACTION OF RHODIUM FROM AQUEOUS NITRIC ACID BY DINONYLNAPHTHALENE SULPHONIC ACID

The extraction of rhodium from aqueous nitric acid using dinonylnapthalene sulphonic acid has been investigated. The extraction occurs readily from 0.1M to 1.0m nitric acid and, since the rhodium is extracted as [Rh(H 2 O) 6 ] 3+ into the inverted micelles of the organic solution,equilibration times...

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Bibliographic Details
Published in:Solvent extraction and ion exchange 1987-08, Vol.5 (4), p.633-647
Main Authors: Patel, N. M., Thornback, J. R.
Format: Article
Language:English
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Summary:The extraction of rhodium from aqueous nitric acid using dinonylnapthalene sulphonic acid has been investigated. The extraction occurs readily from 0.1M to 1.0m nitric acid and, since the rhodium is extracted as [Rh(H 2 O) 6 ] 3+ into the inverted micelles of the organic solution,equilibration times are less than 5 minutes. Extraction is enhanced by the addition of nitrite ion to form [Rh(H 2 O) 5 NO 2 ] 2+ as the extracted species.
ISSN:0736-6299
1532-2262
DOI:10.1080/07366298708918585