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Vaporization thermodynamics of Pd-B(Liquid) and Pd-B-C(Liquid)
The Pd-B and Pd-B-C liquid phases were studied by the Knudsen effusion technique to determine the variation of palladium and boron activity with composition and temperature. Equations are given which describe the thermodynamic properties throughout the liquid phase region. In addition, the phase bou...
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| Published in: | Journal of the less-common metals 1987-11, Vol.135 (2), p.217-228 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c364t-b8c1472fd82987800a61ecc316b519e40ba029dc3a4dc952b0f2a199bdf25c6a3 |
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| cites | cdi_FETCH-LOGICAL-c364t-b8c1472fd82987800a61ecc316b519e40ba029dc3a4dc952b0f2a199bdf25c6a3 |
| container_end_page | 228 |
| container_issue | 2 |
| container_start_page | 217 |
| container_title | Journal of the less-common metals |
| container_volume | 135 |
| creator | Storms, E.K. Szklarz, E.G. |
| description | The Pd-B and Pd-B-C liquid phases were studied by the Knudsen effusion technique to determine the variation of palladium and boron activity with composition and temperature. Equations are given which describe the thermodynamic properties throughout the liquid phase region. In addition, the phase boundary composition was determined between the liquid and the respective multiphase containing excess boron. The phase forms solid boron at 1600 K when the composition reaches Pd
0.55B
0.45 and the palladium activity is 0.0186. Dissolved carbon causes the palladium activity to increase and the phase boundary to shift to a higher boron composition. |
| doi_str_mv | 10.1016/0022-5088(87)90483-8 |
| format | article |
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0.55B
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0.55B
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0.55B
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| fulltext | fulltext |
| identifier | ISSN: 0022-5088 |
| ispartof | Journal of the less-common metals, 1987-11, Vol.135 (2), p.217-228 |
| issn | 0022-5088 |
| language | eng |
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| source | Elsevier SD Backfile Materials Science |
| subjects | Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Metals, semimetals and alloys Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Physics Specific materials Thermal properties of condensed matter Thermal properties of crystalline solids Thermodynamic properties |
| title | Vaporization thermodynamics of Pd-B(Liquid) and Pd-B-C(Liquid) |
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