Stochastic models of pitting corrosion of stainless steels. I: Modeling of the initiation and growth of pits at constant potential

A stochastic model for pit initiation is developed, involving as parameters an initiation frequency for pit nuclei, a death probability for unstable pits, and a critical age which defines the transition between a stable and an unstable pit. Emphasis is placed on validating methods for data analysis...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the Electrochemical Society 1985-08, Vol.132 (8), p.1796-1804
Main Authors: WILLIAMS, D. E, WESTCOTT, C, FLEISCHMANN, M
Format: Article
Language:English
Subjects:
Applied sciences
Corrosion
Corrosion mechanisms
Exact sciences and technology
Metals. Metallurgy
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c299t-49ac77dc1c4b385dd2d97d6f3fbc9a1f52a81133bff0c517d1f873e1e144f23d3
cites
container_end_page 1804
container_issue 8
container_start_page 1796
container_title Journal of the Electrochemical Society
container_volume 132
creator WILLIAMS, D. E
WESTCOTT, C
FLEISCHMANN, M
description A stochastic model for pit initiation is developed, involving as parameters an initiation frequency for pit nuclei, a death probability for unstable pits, and a critical age which defines the transition between a stable and an unstable pit. Emphasis is placed on validating methods for data analysis to recover the parameters of the model from observed current-time series. Such methods are developed and tested using data generated by computer simulation of the process. The expected induction time for stable pit initiation is derived. Results for the statistics of ensembles of current-time transients are given. Methods of analysis of the spectral power density of the current, taking into account the nonstationary process of stable pit propagation, are considered.
doi_str_mv 10.1149/1.2114220
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_24799127</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>24799127</sourcerecordid><originalsourceid>FETCH-LOGICAL-c299t-49ac77dc1c4b385dd2d97d6f3fbc9a1f52a81133bff0c517d1f873e1e144f23d3</originalsourceid><addsrcrecordid>eNqFkU1LAzEQhoMoWKsH_0EOInjYmslmm403KX5BxYN6XtJ8tJFtsm5SxKu_3CxdvHqamfC8z0AGoXMgMwAmrmFGc6WUHKAJCFYVHAAO0YQQKAs2r-AYncT4kUeoGZ-gn9cU1EbG5BTeBm3aiIPFnUvJ-TVWoe9DdMEPjzFJ51sTY-5MBmf46QY_D5kBzUDaGOy8S06mISK9xus-fKXNqIxYpqz0WeQT7kIyPrPtKTqyso3mbKxT9H5_97Z4LJYvD0-L22WhqBCpYEIqzrUCxVZlXWlNteB6bku7UkKCraisAcpyZS1RFXANtualAQOMWVrqcoou996uD587E1OzdVGZtpXehF1sKONCAOX_gllYE6iqDF7tQZV_KfbGNl3vtrL_boA0wzkaaMZzZPZilMqoZGt76ZWLf4G6mguSd_8CogaLSw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>14480155</pqid></control><display><type>article</type><title>Stochastic models of pitting corrosion of stainless steels. I: Modeling of the initiation and growth of pits at constant potential</title><source>Institute of Physics:Jisc Collections:IOP Publishing Read and Publish 2024-2025 (Reading List)</source><creator>WILLIAMS, D. E ; WESTCOTT, C ; FLEISCHMANN, M</creator><creatorcontrib>WILLIAMS, D. E ; WESTCOTT, C ; FLEISCHMANN, M</creatorcontrib><description>A stochastic model for pit initiation is developed, involving as parameters an initiation frequency for pit nuclei, a death probability for unstable pits, and a critical age which defines the transition between a stable and an unstable pit. Emphasis is placed on validating methods for data analysis to recover the parameters of the model from observed current-time series. Such methods are developed and tested using data generated by computer simulation of the process. The expected induction time for stable pit initiation is derived. Results for the statistics of ensembles of current-time transients are given. Methods of analysis of the spectral power density of the current, taking into account the nonstationary process of stable pit propagation, are considered.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2114220</identifier><identifier>CODEN: JESOAN</identifier><language>eng</language><publisher>Pennington, NJ: Electrochemical Society</publisher><subject>Applied sciences ; Corrosion ; Corrosion mechanisms ; Exact sciences and technology ; Metals. Metallurgy</subject><ispartof>Journal of the Electrochemical Society, 1985-08, Vol.132 (8), p.1796-1804</ispartof><rights>1986 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c299t-49ac77dc1c4b385dd2d97d6f3fbc9a1f52a81133bff0c517d1f873e1e144f23d3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=8569027$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>WILLIAMS, D. E</creatorcontrib><creatorcontrib>WESTCOTT, C</creatorcontrib><creatorcontrib>FLEISCHMANN, M</creatorcontrib><title>Stochastic models of pitting corrosion of stainless steels. I: Modeling of the initiation and growth of pits at constant potential</title><title>Journal of the Electrochemical Society</title><description>A stochastic model for pit initiation is developed, involving as parameters an initiation frequency for pit nuclei, a death probability for unstable pits, and a critical age which defines the transition between a stable and an unstable pit. Emphasis is placed on validating methods for data analysis to recover the parameters of the model from observed current-time series. Such methods are developed and tested using data generated by computer simulation of the process. The expected induction time for stable pit initiation is derived. Results for the statistics of ensembles of current-time transients are given. Methods of analysis of the spectral power density of the current, taking into account the nonstationary process of stable pit propagation, are considered.</description><subject>Applied sciences</subject><subject>Corrosion</subject><subject>Corrosion mechanisms</subject><subject>Exact sciences and technology</subject><subject>Metals. Metallurgy</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNqFkU1LAzEQhoMoWKsH_0EOInjYmslmm403KX5BxYN6XtJ8tJFtsm5SxKu_3CxdvHqamfC8z0AGoXMgMwAmrmFGc6WUHKAJCFYVHAAO0YQQKAs2r-AYncT4kUeoGZ-gn9cU1EbG5BTeBm3aiIPFnUvJ-TVWoe9DdMEPjzFJ51sTY-5MBmf46QY_D5kBzUDaGOy8S06mISK9xus-fKXNqIxYpqz0WeQT7kIyPrPtKTqyso3mbKxT9H5_97Z4LJYvD0-L22WhqBCpYEIqzrUCxVZlXWlNteB6bku7UkKCraisAcpyZS1RFXANtualAQOMWVrqcoou996uD587E1OzdVGZtpXehF1sKONCAOX_gllYE6iqDF7tQZV_KfbGNl3vtrL_boA0wzkaaMZzZPZilMqoZGt76ZWLf4G6mguSd_8CogaLSw</recordid><startdate>19850801</startdate><enddate>19850801</enddate><creator>WILLIAMS, D. E</creator><creator>WESTCOTT, C</creator><creator>FLEISCHMANN, M</creator><general>Electrochemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7T2</scope><scope>7U2</scope><scope>C1K</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19850801</creationdate><title>Stochastic models of pitting corrosion of stainless steels. I: Modeling of the initiation and growth of pits at constant potential</title><author>WILLIAMS, D. E ; WESTCOTT, C ; FLEISCHMANN, M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c299t-49ac77dc1c4b385dd2d97d6f3fbc9a1f52a81133bff0c517d1f873e1e144f23d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>Applied sciences</topic><topic>Corrosion</topic><topic>Corrosion mechanisms</topic><topic>Exact sciences and technology</topic><topic>Metals. Metallurgy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>WILLIAMS, D. E</creatorcontrib><creatorcontrib>WESTCOTT, C</creatorcontrib><creatorcontrib>FLEISCHMANN, M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Safety Science and Risk</collection><collection>Environmental Sciences and Pollution Management</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>WILLIAMS, D. E</au><au>WESTCOTT, C</au><au>FLEISCHMANN, M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stochastic models of pitting corrosion of stainless steels. I: Modeling of the initiation and growth of pits at constant potential</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>1985-08-01</date><risdate>1985</risdate><volume>132</volume><issue>8</issue><spage>1796</spage><epage>1804</epage><pages>1796-1804</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>A stochastic model for pit initiation is developed, involving as parameters an initiation frequency for pit nuclei, a death probability for unstable pits, and a critical age which defines the transition between a stable and an unstable pit. Emphasis is placed on validating methods for data analysis to recover the parameters of the model from observed current-time series. Such methods are developed and tested using data generated by computer simulation of the process. The expected induction time for stable pit initiation is derived. Results for the statistics of ensembles of current-time transients are given. Methods of analysis of the spectral power density of the current, taking into account the nonstationary process of stable pit propagation, are considered.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2114220</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0013-4651
ispartof Journal of the Electrochemical Society, 1985-08, Vol.132 (8), p.1796-1804
issn 0013-4651
1945-7111
language eng
recordid cdi_proquest_miscellaneous_24799127
source Institute of Physics:Jisc Collections:IOP Publishing Read and Publish 2024-2025 (Reading List)
subjects Applied sciences
Corrosion
Corrosion mechanisms
Exact sciences and technology
Metals. Metallurgy
title Stochastic models of pitting corrosion of stainless steels. I: Modeling of the initiation and growth of pits at constant potential
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-22T23%3A15%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Stochastic%20models%20of%20pitting%20corrosion%20of%20stainless%20steels.%20I:%20Modeling%20of%20the%20initiation%20and%20growth%20of%20pits%20at%20constant%20potential&rft.jtitle=Journal%20of%20the%20Electrochemical%20Society&rft.au=WILLIAMS,%20D.%20E&rft.date=1985-08-01&rft.volume=132&rft.issue=8&rft.spage=1796&rft.epage=1804&rft.pages=1796-1804&rft.issn=0013-4651&rft.eissn=1945-7111&rft.coden=JESOAN&rft_id=info:doi/10.1149/1.2114220&rft_dat=%3Cproquest_cross%3E24799127%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c299t-49ac77dc1c4b385dd2d97d6f3fbc9a1f52a81133bff0c517d1f873e1e144f23d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=14480155&rft_id=info:pmid/&rfr_iscdi=true