Efficient Energy Transfer in Te4+-Doped Cs2ZrCl6 Vacancy-Ordered Perovskites and Ultrahigh Moisture Stability via A‑Site Rb-Alloying Strategy

• Published in: The journal of physical chemistry letters 2021-02, Vol.12 (7), p.1829-1837
• Main Authors: Chang, Tong, Wei, Qilin, Zeng, Ruosheng, Cao, Sheng, Zhao, Jialong, Zou, Bingsuo
• Format: Article
• Language: English
• Subjects: Physical Insights into Materials and Molecular Properties
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.1c00255

As an effective method to improve the optical properties and stability of perovskite matrix, doped halide perovskites have attracted extensive attention in the field of optoelectronic applications. Herein, a series of all inorganic lead-free Te4+-doped Cs2ZrCl6 vacancy-ordered perovskites were successfully synthesized with different Te-doping concentrations by a solvothermal method, and deliberate Te4+-doping results in green-yellow triplet self-trapped exciton (STE) emission with a high photoluminescence quantum yield (PLQY) of 49.0%. The efficient energy transfer was observed from singlet to triplet emission. Further, the effects of A-site Rb alloying on the optical properties and stability were investigated. We found that A-site Rb alloying and C-site cohalogenation did not change the luminescence properties of Te4+, but the addition of a small amount of Rb+ can improve the PL intensity and moisture stability. Our results provide physical insights into the nS2 Te4+-ion-doping-induced emissive mechanism and shed light on improving the environmental stability for further applications.