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Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water
Two tetraphenylethene-based tetracationic cyclophanes 1 and 2 were synthesized via a one-step S N 2 reaction without using any template. Based on the fluorescence and rotational conformation of the tetraphenylethene units, these water-soluble cyclophanes exhibited adaptive chirality with dual respon...
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| Published in: | Chemical communications (Cambridge, England) England), 2021-03, Vol.57 (25), p.3135-3138 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c337t-fa0d32fae442c90ba49441b6f0b0d8e250cc0ed128fe5a4c535c53c5195319683 |
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| cites | cdi_FETCH-LOGICAL-c337t-fa0d32fae442c90ba49441b6f0b0d8e250cc0ed128fe5a4c535c53c5195319683 |
| container_end_page | 3138 |
| container_issue | 25 |
| container_start_page | 3135 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 57 |
| creator | Zhang, Haiyang Cheng, Lin Nian, Hao Du, Jiang Chen, Tao Cao, Liping |
| description | Two tetraphenylethene-based tetracationic cyclophanes 1 and 2 were synthesized
via
a one-step
S
N
2 reaction without using any template. Based on the fluorescence and rotational conformation of the tetraphenylethene units, these water-soluble cyclophanes exhibited adaptive chirality with dual responses of turn-on fluorescence and induced circular dichroism when combined with nucleotides and DNA in water.
Tetraphenylethene-based tetracationic cyclophanes exhibited adaptive chirality with fluorescence enhancement or/and induced CD when combined with ATP and DNA
via
hydrophobic effects and electrostatic interactions in water. |
| doi_str_mv | 10.1039/d1cc00303h |
| format | article |
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via
a one-step
S
N
2 reaction without using any template. Based on the fluorescence and rotational conformation of the tetraphenylethene units, these water-soluble cyclophanes exhibited adaptive chirality with dual responses of turn-on fluorescence and induced circular dichroism when combined with nucleotides and DNA in water.
Tetraphenylethene-based tetracationic cyclophanes exhibited adaptive chirality with fluorescence enhancement or/and induced CD when combined with ATP and DNA
via
hydrophobic effects and electrostatic interactions in water.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc00303h</identifier><identifier>PMID: 33634292</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chirality ; Crystallography ; Dichroism ; Fluorescence ; Format ; NMR ; Nuclear magnetic resonance ; Nucleotides</subject><ispartof>Chemical communications (Cambridge, England), 2021-03, Vol.57 (25), p.3135-3138</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-fa0d32fae442c90ba49441b6f0b0d8e250cc0ed128fe5a4c535c53c5195319683</citedby><cites>FETCH-LOGICAL-c337t-fa0d32fae442c90ba49441b6f0b0d8e250cc0ed128fe5a4c535c53c5195319683</cites><orcidid>0000-0001-6686-1821 ; 0000-0002-1747-6107</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33634292$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Haiyang</creatorcontrib><creatorcontrib>Cheng, Lin</creatorcontrib><creatorcontrib>Nian, Hao</creatorcontrib><creatorcontrib>Du, Jiang</creatorcontrib><creatorcontrib>Chen, Tao</creatorcontrib><creatorcontrib>Cao, Liping</creatorcontrib><title>Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Two tetraphenylethene-based tetracationic cyclophanes 1 and 2 were synthesized
via
a one-step
S
N
2 reaction without using any template. Based on the fluorescence and rotational conformation of the tetraphenylethene units, these water-soluble cyclophanes exhibited adaptive chirality with dual responses of turn-on fluorescence and induced circular dichroism when combined with nucleotides and DNA in water.
Tetraphenylethene-based tetracationic cyclophanes exhibited adaptive chirality with fluorescence enhancement or/and induced CD when combined with ATP and DNA
via
hydrophobic effects and electrostatic interactions in water.</description><subject>Chirality</subject><subject>Crystallography</subject><subject>Dichroism</subject><subject>Fluorescence</subject><subject>Format</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Nucleotides</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkU1r3DAQhkVpaD4vvScIcgkBN5Ilea1j2H6kEMilhdyMPBpjBa_lSnLC_o784WrrNIEIxEijZ16N9BLymbMvnAl9ZTkAY4KJ_gM54KKShZL1_cfdWuliJaTaJ4cxPrA8uKo_kX0hKiFLXR6Q52trpuQekULvghlc2lLfUbPsaMIUzNTjuB0w5YBFayLaJQ8mOT86oLCFwU-9GTHSJ5d6audcGzBOfow5lwW7YfY5ATgCUjNaCi7APJhArYM-eBc31I30ySQMx2SvM0PEk5d4RH5___ZrfVPc3v34ub6-LUCIVSo6w6woO4NSlqBZa6SWkrdVx1pmaywVy9-Clpd1h8pIUELlCYprJbiuanFELhbdKfg_M8bUbFzucBjyQ_wcmzILllrWfIeev0Mf_BzG3F2T75GrSldKZupyoSD4GAN2zRTcxoRtw1mzs6r5ytfrf1bdZPjsRXJuN2hf0f_eZOB0AUKE19M3r8Vfb8Sbfg</recordid><startdate>20210328</startdate><enddate>20210328</enddate><creator>Zhang, Haiyang</creator><creator>Cheng, Lin</creator><creator>Nian, Hao</creator><creator>Du, Jiang</creator><creator>Chen, Tao</creator><creator>Cao, Liping</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6686-1821</orcidid><orcidid>https://orcid.org/0000-0002-1747-6107</orcidid></search><sort><creationdate>20210328</creationdate><title>Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water</title><author>Zhang, Haiyang ; Cheng, Lin ; Nian, Hao ; Du, Jiang ; Chen, Tao ; Cao, Liping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-fa0d32fae442c90ba49441b6f0b0d8e250cc0ed128fe5a4c535c53c5195319683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chirality</topic><topic>Crystallography</topic><topic>Dichroism</topic><topic>Fluorescence</topic><topic>Format</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Nucleotides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Haiyang</creatorcontrib><creatorcontrib>Cheng, Lin</creatorcontrib><creatorcontrib>Nian, Hao</creatorcontrib><creatorcontrib>Du, Jiang</creatorcontrib><creatorcontrib>Chen, Tao</creatorcontrib><creatorcontrib>Cao, Liping</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Haiyang</au><au>Cheng, Lin</au><au>Nian, Hao</au><au>Du, Jiang</au><au>Chen, Tao</au><au>Cao, Liping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2021-03-28</date><risdate>2021</risdate><volume>57</volume><issue>25</issue><spage>3135</spage><epage>3138</epage><pages>3135-3138</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Two tetraphenylethene-based tetracationic cyclophanes 1 and 2 were synthesized
via
a one-step
S
N
2 reaction without using any template. Based on the fluorescence and rotational conformation of the tetraphenylethene units, these water-soluble cyclophanes exhibited adaptive chirality with dual responses of turn-on fluorescence and induced circular dichroism when combined with nucleotides and DNA in water.
Tetraphenylethene-based tetracationic cyclophanes exhibited adaptive chirality with fluorescence enhancement or/and induced CD when combined with ATP and DNA
via
hydrophobic effects and electrostatic interactions in water.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>33634292</pmid><doi>10.1039/d1cc00303h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-6686-1821</orcidid><orcidid>https://orcid.org/0000-0002-1747-6107</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-03, Vol.57 (25), p.3135-3138 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2494294818 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Chirality Crystallography Dichroism Fluorescence Format NMR Nuclear magnetic resonance Nucleotides |
| title | Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water |
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