Polymerization of vinyl monomers initiated by peroxide-geminal bis-sulphide systems

It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products of the in...

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Bibliographic Details
Published in:European polymer journal 1988, Vol.24 (6), p.579-583
Main Authors: Puzin, Yu.I., Leplyanin, G.V., Shaul'skii, Yu.M., Tolstikov, G.A.
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Summary:It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products of the interaction of the components.
ISSN:0014-3057
1873-1945
DOI:10.1016/0014-3057(88)90053-5