Thermodynamics applied to ionic transport in glasses

The main characteristics of ionic conductivity for inorganic glasses have been reviewed as a function of temperature and composition. A microscopic model for ionic transport, coherent with the weak electrolyte theory, is suggested. On a macroscopic level, the correlation of conductivity data to part...

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Bibliographic Details
Published in:Solid state ionics 1990, Vol.40, p.595-604
Main Authors: Souquet, J.L., Perera, W.G.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Transport properties of condensed matter (nonelectronic)
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Summary:The main characteristics of ionic conductivity for inorganic glasses have been reviewed as a function of temperature and composition. A microscopic model for ionic transport, coherent with the weak electrolyte theory, is suggested. On a macroscopic level, the correlation of conductivity data to partial thermodynamic functions allows the extension of solution thermodynamics to glassy electrolytes.
ISSN:0167-2738
1872-7689
DOI:10.1016/0167-2738(90)90078-6