Electron Beam Irradiation‐Induced Formation of Defect‐Rich Zeolites under Ambient Condition within Minutes

Zeolites are a well‐known family of microporous aluminosilicate crystals with a wide range of applications. Their industrial synthetic method under hydrothermal condition requires elevated temperature and long crystallization time and is therefore quite energy‐consuming. Herein, we utilize high‐ener...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2021-06, Vol.60 (27), p.14858-14863
Main Authors: Chen, Junchang, Zhang, Mingxing, Shu, Jie, Yuan, Mengjia, Yan, Wenfu, Bai, Pu, He, Linwei, Shen, Nannan, Gong, Shicheng, Zhang, Duo, Li, Jiong, Hu, Jiangtao, Li, Rong, Wu, Guozhong, Chai, Zhifang, Yu, Jihong, Wang, Shuao
Format: Article
Language:English
Subjects:
Aluminosilicates
Aluminum silicates
Crystal defects
Crystallization
Crystals
defects
electron beam irradiation
Electron beams
Electron irradiation
Energy
Energy conservation
Energy sources
Etching
heavy metal ions
Heavy metals
High temperature
Hydrothermal reactions
Irradiation
Radiation
Radiation dosage
Temperature requirements
Zeolites
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Summary:Zeolites are a well‐known family of microporous aluminosilicate crystals with a wide range of applications. Their industrial synthetic method under hydrothermal condition requires elevated temperature and long crystallization time and is therefore quite energy‐consuming. Herein, we utilize high‐energy electron beam irradiation generated by an industrial accelerator as a distinct type of energy source to activate the formation reaction of Na‐A zeolite. The initial efforts afford an attractive reaction process that can be achieved under ambient conditions and completed within minutes with almost quantitative yield, leading to notable energy saving of one order of magnitude compared to the hydrothermal reaction. More importantly, electron beam irradiation simultaneously exhibits an etching effect during the formation of zeolite generating a series of crystal defects and additional pore windows that can be controlled by irradiation dose. These observations give rise to significantly enhanced surface area and heavy metal removal capabilities in comparison with Na‐A zeolite synthesized hydrothermally. Finally, we show that this method can be applied to many other types of zeolites. Defect‐rich Na‐A zeolites were synthesized by electron beam irradiation under ambient condition within minutes. The as‐synthesized Na‐A shows enhanced adsorption performance for CO2 and heavy ions in comparison with samples synthesized hydrothermally.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202103766