Uniform 1D Micelles and Patchy & Block Comicelles via Scalable, One-Step Crystallization-Driven Block Copolymer Self-Assembly

Fiber-like (1D) core-crystalline micelles of uniform length can be obtained in protocols involving multiple steps from block copolymers (BCPs) in which crystallization of the core-forming polymer drives the self-assembly. Here we report a systematic study that shows that adding small amounts (

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Bibliographic Details
Published in:Journal of the American Chemical Society 2021-04, Vol.143 (16), p.6266-6280
Main Authors: Song, Shaofei, Liu, Xuemin, Nikbin, Ehsan, Howe, Jane Y, Yu, Qing, Manners, Ian, Winnik, Mitchell A
Format: Article
Language:English
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Description
Summary:Fiber-like (1D) core-crystalline micelles of uniform length can be obtained in protocols involving multiple steps from block copolymers (BCPs) in which crystallization of the core-forming polymer drives the self-assembly. Here we report a systematic study that shows that adding small amounts (
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.1c02395