Construction of Silver Clusters Capped by Zwitterionic Ethynide Ligands

A zwitterionic ligand 3-(triethylammonio)­propyne (TAP) has been employed to construct nine silver ethynide compounds for the first time. Single-crystal X-ray analyses reveal that compounds 1 and 2 are silver ethynide assemblies based on the Ag3 subunits and clusters 3–8 are small discrete clusters...

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Published in:Inorganic chemistry 2021-05, Vol.60 (9), p.6276-6282
Main Authors: Shen, Yang-Lin, Jin, Jun-Ling, Fang, Jun-Jie, Liu, Zheng, Shi, Jian-Lin, Xie, Yun-Peng, Lu, Xing
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container_issue 9
container_start_page 6276
container_title Inorganic chemistry
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creator Shen, Yang-Lin
Jin, Jun-Ling
Fang, Jun-Jie
Liu, Zheng
Shi, Jian-Lin
Xie, Yun-Peng
Lu, Xing
description A zwitterionic ligand 3-(triethylammonio)­propyne (TAP) has been employed to construct nine silver ethynide compounds for the first time. Single-crystal X-ray analyses reveal that compounds 1 and 2 are silver ethynide assemblies based on the Ag3 subunits and clusters 3–8 are small discrete clusters of Ag3, Ag6, Ag8, and Ag12, respectively, ligated by the bulky TAP ligand with different auxiliary ligands. In addition, upon acquiring the tripod-like t BuPO3 2–, a unprecedented 80 nuclei silver ethynide cluster was isolated and determined to be [(CF3CO2)5@Ag80(TAP)14( t BuPO3)16(CF3CO2)24]19+ by crystallography and thermogravimetric analysis. The C 1 symmetry of Ag80 was deconstructed to be two [Ag40(TAP)7( t BuPO3)8(CF3CO2)12]12+ secondary building subunits arranged in a cross way, with five CF3CO2 – trapped in the center. These results highlight that the elaborate selection of ethynide ligands is of great importance in the synthesis of novel silver ethynide clusters.
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title Construction of Silver Clusters Capped by Zwitterionic Ethynide Ligands
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