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Hydrothermal synthesis, structure, and sorption properties of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)]
Yellow plates of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)], (1), obtained in 60% yield from the reaction of Cs 2MoO 4, Mo, H 3PO 4, and H 2O in a mole ratio of 5:1:30:57 for 24 hrs at 200°C, crystallize in the monoclinic space group P2 1 a with a = 9.166(4), b = 9.073(2), c = 15.808(3)Å, β = 96.85°, V = 1305...
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| Published in: | Journal of solid state chemistry 1991-12, Vol.95 (2), p.283-288 |
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| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c430t-e83481849aad0c767bfe58c9b8a43642373cf6c7be8d72c26a833a440d926c5f3 |
| container_end_page | 288 |
| container_issue | 2 |
| container_start_page | 283 |
| container_title | Journal of solid state chemistry |
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| creator | Mundi, Linda A. Yacullo, L. Haushalter, Robert C. |
| description | Yellow plates of Cs(H
3O)[Mo
2O
2(PO
4)
2(HPO
4)],
(1), obtained in 60% yield from the reaction of Cs
2MoO
4, Mo, H
3PO
4, and H
2O in a mole ratio of 5:1:30:57 for 24 hrs at 200°C, crystallize in the monoclinic space group
P2
1
a
with
a = 9.166(4),
b = 9.073(2),
c = 15.808(3)Å, β = 96.85°,
V = 1305(1)Å
3,
Z = 4, and
R(
R
w
) = 0.087(0.085). The structure has MoOPO
4-like layers held together with HPO
4 groups and is structurally similar to (VO)
2(SO
4)
2(H
2SO
4). The interlamellar space is compartmentalized into tunnels containing one-dimensional H-bonded strings of HPO
4 groups alternating with strings of Cs
+ and H
3O
+ cations. It is possible to remove water from the structure in a reversible manner as shown from water absorption isotherms. This same composition framework was prepared in a different crystal system and with a different cation by Clearfield and Peascoe (see
J. Solid State Chem.
95(1), 83 (1991)). |
| doi_str_mv | 10.1016/0022-4596(91)90107-S |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_25240249</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>002245969190107S</els_id><sourcerecordid>25240249</sourcerecordid><originalsourceid>FETCH-LOGICAL-c430t-e83481849aad0c767bfe58c9b8a43642373cf6c7be8d72c26a833a440d926c5f3</originalsourceid><addsrcrecordid>eNp9kF1LMzEQhYMoWD_-gRe5EGnB1XxtdnMjvBS1glJBBUE0pNlZjGw3fTNbof_erRUvvTrn4pkzM4eQI87OOOP6nDEhMpUbPTR8ZBhnRfawRQacmTwrhH7eJoNfZJfsIX4wxnleqgF5m6yqFLt3SHPXUFy1vcWApxS7tPTdMsEpdW1FMaZFF2JLFykuIHUBkMaajnE4oXI6ermLVEypGN5PqRr1Ovk2rwdkp3YNwuGP7pOnq8vH8SS7nV7fjP_dZl5J1mVQSlXyUhnnKuYLXcxqyEtvZqVTUishC-lr7YsZlFUhvNCulNIpxSojtM9ruU9ONrn9ef-XgJ2dB_TQNK6FuEQrcqGYUKYH1Qb0KSImqO0ihblLK8uZXZdp103ZdVPWcPtdpn3ox45_8h1619TJtT7g72yeayGZ6rGLDQb9r58BkkUfoPVQhQS-s1UMf-_5AqOUhSI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>25240249</pqid></control><display><type>article</type><title>Hydrothermal synthesis, structure, and sorption properties of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)]</title><source>Backfile Package - Materials Science [YMS]</source><source>Backfile Package - Physics General (Legacy) [YPA]</source><creator>Mundi, Linda A. ; Yacullo, L. ; Haushalter, Robert C.</creator><creatorcontrib>Mundi, Linda A. ; Yacullo, L. ; Haushalter, Robert C.</creatorcontrib><description>Yellow plates of Cs(H
3O)[Mo
2O
2(PO
4)
2(HPO
4)],
(1), obtained in 60% yield from the reaction of Cs
2MoO
4, Mo, H
3PO
4, and H
2O in a mole ratio of 5:1:30:57 for 24 hrs at 200°C, crystallize in the monoclinic space group
P2
1
a
with
a = 9.166(4),
b = 9.073(2),
c = 15.808(3)Å, β = 96.85°,
V = 1305(1)Å
3,
Z = 4, and
R(
R
w
) = 0.087(0.085). The structure has MoOPO
4-like layers held together with HPO
4 groups and is structurally similar to (VO)
2(SO
4)
2(H
2SO
4). The interlamellar space is compartmentalized into tunnels containing one-dimensional H-bonded strings of HPO
4 groups alternating with strings of Cs
+ and H
3O
+ cations. It is possible to remove water from the structure in a reversible manner as shown from water absorption isotherms. This same composition framework was prepared in a different crystal system and with a different cation by Clearfield and Peascoe (see
J. Solid State Chem.
95(1), 83 (1991)).</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/0022-4596(91)90107-S</identifier><identifier>CODEN: JSSCBI</identifier><language>eng</language><publisher>San Diego, CA: Elsevier Inc</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Inorganic compounds ; Metal complexes ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Journal of solid state chemistry, 1991-12, Vol.95 (2), p.283-288</ispartof><rights>1991</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-e83481849aad0c767bfe58c9b8a43642373cf6c7be8d72c26a833a440d926c5f3</citedby><cites>FETCH-LOGICAL-c430t-e83481849aad0c767bfe58c9b8a43642373cf6c7be8d72c26a833a440d926c5f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/002245969190107S$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3553,3630,27923,27924,46003,46011</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5562304$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mundi, Linda A.</creatorcontrib><creatorcontrib>Yacullo, L.</creatorcontrib><creatorcontrib>Haushalter, Robert C.</creatorcontrib><title>Hydrothermal synthesis, structure, and sorption properties of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)]</title><title>Journal of solid state chemistry</title><description>Yellow plates of Cs(H
3O)[Mo
2O
2(PO
4)
2(HPO
4)],
(1), obtained in 60% yield from the reaction of Cs
2MoO
4, Mo, H
3PO
4, and H
2O in a mole ratio of 5:1:30:57 for 24 hrs at 200°C, crystallize in the monoclinic space group
P2
1
a
with
a = 9.166(4),
b = 9.073(2),
c = 15.808(3)Å, β = 96.85°,
V = 1305(1)Å
3,
Z = 4, and
R(
R
w
) = 0.087(0.085). The structure has MoOPO
4-like layers held together with HPO
4 groups and is structurally similar to (VO)
2(SO
4)
2(H
2SO
4). The interlamellar space is compartmentalized into tunnels containing one-dimensional H-bonded strings of HPO
4 groups alternating with strings of Cs
+ and H
3O
+ cations. It is possible to remove water from the structure in a reversible manner as shown from water absorption isotherms. This same composition framework was prepared in a different crystal system and with a different cation by Clearfield and Peascoe (see
J. Solid State Chem.
95(1), 83 (1991)).</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Inorganic compounds</subject><subject>Metal complexes</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNp9kF1LMzEQhYMoWD_-gRe5EGnB1XxtdnMjvBS1glJBBUE0pNlZjGw3fTNbof_erRUvvTrn4pkzM4eQI87OOOP6nDEhMpUbPTR8ZBhnRfawRQacmTwrhH7eJoNfZJfsIX4wxnleqgF5m6yqFLt3SHPXUFy1vcWApxS7tPTdMsEpdW1FMaZFF2JLFykuIHUBkMaajnE4oXI6ermLVEypGN5PqRr1Ovk2rwdkp3YNwuGP7pOnq8vH8SS7nV7fjP_dZl5J1mVQSlXyUhnnKuYLXcxqyEtvZqVTUishC-lr7YsZlFUhvNCulNIpxSojtM9ruU9ONrn9ef-XgJ2dB_TQNK6FuEQrcqGYUKYH1Qb0KSImqO0ihblLK8uZXZdp103ZdVPWcPtdpn3ox45_8h1619TJtT7g72yeayGZ6rGLDQb9r58BkkUfoPVQhQS-s1UMf-_5AqOUhSI</recordid><startdate>19911201</startdate><enddate>19911201</enddate><creator>Mundi, Linda A.</creator><creator>Yacullo, L.</creator><creator>Haushalter, Robert C.</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>19911201</creationdate><title>Hydrothermal synthesis, structure, and sorption properties of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)]</title><author>Mundi, Linda A. ; Yacullo, L. ; Haushalter, Robert C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-e83481849aad0c767bfe58c9b8a43642373cf6c7be8d72c26a833a440d926c5f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Inorganic compounds</topic><topic>Metal complexes</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mundi, Linda A.</creatorcontrib><creatorcontrib>Yacullo, L.</creatorcontrib><creatorcontrib>Haushalter, Robert C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mundi, Linda A.</au><au>Yacullo, L.</au><au>Haushalter, Robert C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrothermal synthesis, structure, and sorption properties of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)]</atitle><jtitle>Journal of solid state chemistry</jtitle><date>1991-12-01</date><risdate>1991</risdate><volume>95</volume><issue>2</issue><spage>283</spage><epage>288</epage><pages>283-288</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><coden>JSSCBI</coden><abstract>Yellow plates of Cs(H
3O)[Mo
2O
2(PO
4)
2(HPO
4)],
(1), obtained in 60% yield from the reaction of Cs
2MoO
4, Mo, H
3PO
4, and H
2O in a mole ratio of 5:1:30:57 for 24 hrs at 200°C, crystallize in the monoclinic space group
P2
1
a
with
a = 9.166(4),
b = 9.073(2),
c = 15.808(3)Å, β = 96.85°,
V = 1305(1)Å
3,
Z = 4, and
R(
R
w
) = 0.087(0.085). The structure has MoOPO
4-like layers held together with HPO
4 groups and is structurally similar to (VO)
2(SO
4)
2(H
2SO
4). The interlamellar space is compartmentalized into tunnels containing one-dimensional H-bonded strings of HPO
4 groups alternating with strings of Cs
+ and H
3O
+ cations. It is possible to remove water from the structure in a reversible manner as shown from water absorption isotherms. This same composition framework was prepared in a different crystal system and with a different cation by Clearfield and Peascoe (see
J. Solid State Chem.
95(1), 83 (1991)).</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><doi>10.1016/0022-4596(91)90107-S</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of solid state chemistry, 1991-12, Vol.95 (2), p.283-288 |
| issn | 0022-4596 1095-726X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_25240249 |
| source | Backfile Package - Materials Science [YMS]; Backfile Package - Physics General (Legacy) [YPA] |
| subjects | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Metal complexes Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Hydrothermal synthesis, structure, and sorption properties of Cs(H 3O)[Mo 2O 2(PO 4) 2(HPO 4)] |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-13T06%3A37%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hydrothermal%20synthesis,%20structure,%20and%20sorption%20properties%20of%20Cs(H%203O)%5BMo%202O%202(PO%204)%202(HPO%204)%5D&rft.jtitle=Journal%20of%20solid%20state%20chemistry&rft.au=Mundi,%20Linda%20A.&rft.date=1991-12-01&rft.volume=95&rft.issue=2&rft.spage=283&rft.epage=288&rft.pages=283-288&rft.issn=0022-4596&rft.eissn=1095-726X&rft.coden=JSSCBI&rft_id=info:doi/10.1016/0022-4596(91)90107-S&rft_dat=%3Cproquest_cross%3E25240249%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c430t-e83481849aad0c767bfe58c9b8a43642373cf6c7be8d72c26a833a440d926c5f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=25240249&rft_id=info:pmid/&rfr_iscdi=true |