Retention of a Four-Fold Interpenetrating Cadmium–Organic Framework through a Three-Step Single Crystal Transformation

Controlled hydration leads to four derivatives of a metal–organic framework consisting of cadmium ions, N 1,N 1,N 4,N 4-tetrakis­(4-(pyridin-4-yl)­phenyl)­benzene-1,4-diamine, and coordinated and free nitrates. The balance of water coordination and the multitude of bonding of the weakly coordinated...

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Published in:Inorganic chemistry 2021-06, Vol.60 (11), p.8331-8338
Main Authors: Li, Jia-Qian, Ke, Si-Wen, Yan, Tong, Li, Yu-Yang, Zhou, Yan, Kurmoo, Mohamedally, Su, Jian, Zuo, Jing-Lin
Format: Article
Language:English
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Summary:Controlled hydration leads to four derivatives of a metal–organic framework consisting of cadmium ions, N 1,N 1,N 4,N 4-tetrakis­(4-(pyridin-4-yl)­phenyl)­benzene-1,4-diamine, and coordinated and free nitrates. The balance of water coordination and the multitude of bonding of the weakly coordinated nitrate lead to a progressive change in the coordination number of the Cd2+ ions from eight to seven to six without great perturbation to the 4-fold interpenetration three-dimensional framework.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.1c01105