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A Rhodamine‐based Fluorescent Chemodosimeter for Au3+ in Aqueous Solution and Living Cells
A highly selective rhodamine hydrazide-based fluorescent chemosensor for Au 3+ detection was developed. The aqueous solution of rhodamine N -hydroxysemicarbazide ( RHS ), in the presence of Au 3+ , exhibited a significant 55-fold turn-on fluorescence response at 591 nm and a colorimetric change from...
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| Published in: | Journal of fluorescence 2021-07, Vol.31 (4), p.1211-1218 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c282t-ff16f647681d5bf544a951b76960fab2a1d8cb6c67af773deb197c095f78e2483 |
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| cites | cdi_FETCH-LOGICAL-c282t-ff16f647681d5bf544a951b76960fab2a1d8cb6c67af773deb197c095f78e2483 |
| container_end_page | 1218 |
| container_issue | 4 |
| container_start_page | 1211 |
| container_title | Journal of fluorescence |
| container_volume | 31 |
| creator | Pitsanuwong, Chariwat Boonwan, Juthamanee Chomngam, Sinchai Wechakorn, Kanokorn Kanjanasirirat, Phongthon Pewkliang, Yongyut Borwornpinyo, Suparerk Kongsaeree, Palangpon |
| description | A highly selective rhodamine hydrazide-based fluorescent chemosensor for Au
3+
detection was developed. The aqueous solution of rhodamine
N
-hydroxysemicarbazide (
RHS
), in the presence of Au
3+
, exhibited a significant 55-fold turn-on fluorescence response at 591 nm and a colorimetric change from colorless to pink. Other interested ions including Li
+
, Na
+
, K
+
, Cs
+
, Mg
2+
, Ca
2+
, Ba
2+
, Pb
2+
, Mn
2+
, Co
2+
, Ni
2+
, Ag
+
, Cd
2+
, Cu
2+
, Hg
2+
, Zn
2+
, Sn
2+
, Fe
2+
, Fe
3+
, Cr
3+
, Ce
3+
did not induce any distinct color/spectral changes. The irreversible detection mechanism occurred via Au
3+
-promoted 5-
exo
-
trig
ring closure to yield 1,3,4-oxadiazole-2-one product. The
RHS
probe is non-responsive to other biologically relevant metal ions and the limit of detection for Au
3+
was calculated to be 0.5 µM with a linear range of 0 to 90 µM. Fluorescence bioimaging of Au
3+
in HepG2 cells was also successfully demonstrated. |
| doi_str_mv | 10.1007/s10895-021-02725-0 |
| format | article |
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3+
detection was developed. The aqueous solution of rhodamine
N
-hydroxysemicarbazide (
RHS
), in the presence of Au
3+
, exhibited a significant 55-fold turn-on fluorescence response at 591 nm and a colorimetric change from colorless to pink. Other interested ions including Li
+
, Na
+
, K
+
, Cs
+
, Mg
2+
, Ca
2+
, Ba
2+
, Pb
2+
, Mn
2+
, Co
2+
, Ni
2+
, Ag
+
, Cd
2+
, Cu
2+
, Hg
2+
, Zn
2+
, Sn
2+
, Fe
2+
, Fe
3+
, Cr
3+
, Ce
3+
did not induce any distinct color/spectral changes. The irreversible detection mechanism occurred via Au
3+
-promoted 5-
exo
-
trig
ring closure to yield 1,3,4-oxadiazole-2-one product. The
RHS
probe is non-responsive to other biologically relevant metal ions and the limit of detection for Au
3+
was calculated to be 0.5 µM with a linear range of 0 to 90 µM. Fluorescence bioimaging of Au
3+
in HepG2 cells was also successfully demonstrated.</description><identifier>ISSN: 1053-0509</identifier><identifier>ISSN: 1573-4994</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-021-02725-0</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analytical Chemistry ; Aqueous solutions ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Calcium ions ; Cerium ; Chemical sensors ; Chemoreceptors ; Cobalt ; Colorimetry ; Fluorescence ; Manganese ; Medical imaging ; Original Article ; Rhodamine ; Silver ; Tin</subject><ispartof>Journal of fluorescence, 2021-07, Vol.31 (4), p.1211-1218</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c282t-ff16f647681d5bf544a951b76960fab2a1d8cb6c67af773deb197c095f78e2483</citedby><cites>FETCH-LOGICAL-c282t-ff16f647681d5bf544a951b76960fab2a1d8cb6c67af773deb197c095f78e2483</cites><orcidid>0000-0003-2689-9651</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Pitsanuwong, Chariwat</creatorcontrib><creatorcontrib>Boonwan, Juthamanee</creatorcontrib><creatorcontrib>Chomngam, Sinchai</creatorcontrib><creatorcontrib>Wechakorn, Kanokorn</creatorcontrib><creatorcontrib>Kanjanasirirat, Phongthon</creatorcontrib><creatorcontrib>Pewkliang, Yongyut</creatorcontrib><creatorcontrib>Borwornpinyo, Suparerk</creatorcontrib><creatorcontrib>Kongsaeree, Palangpon</creatorcontrib><title>A Rhodamine‐based Fluorescent Chemodosimeter for Au3+ in Aqueous Solution and Living Cells</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><description>A highly selective rhodamine hydrazide-based fluorescent chemosensor for Au
3+
detection was developed. The aqueous solution of rhodamine
N
-hydroxysemicarbazide (
RHS
), in the presence of Au
3+
, exhibited a significant 55-fold turn-on fluorescence response at 591 nm and a colorimetric change from colorless to pink. Other interested ions including Li
+
, Na
+
, K
+
, Cs
+
, Mg
2+
, Ca
2+
, Ba
2+
, Pb
2+
, Mn
2+
, Co
2+
, Ni
2+
, Ag
+
, Cd
2+
, Cu
2+
, Hg
2+
, Zn
2+
, Sn
2+
, Fe
2+
, Fe
3+
, Cr
3+
, Ce
3+
did not induce any distinct color/spectral changes. The irreversible detection mechanism occurred via Au
3+
-promoted 5-
exo
-
trig
ring closure to yield 1,3,4-oxadiazole-2-one product. The
RHS
probe is non-responsive to other biologically relevant metal ions and the limit of detection for Au
3+
was calculated to be 0.5 µM with a linear range of 0 to 90 µM. Fluorescence bioimaging of Au
3+
in HepG2 cells was also successfully demonstrated.</description><subject>Analytical Chemistry</subject><subject>Aqueous solutions</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Calcium ions</subject><subject>Cerium</subject><subject>Chemical sensors</subject><subject>Chemoreceptors</subject><subject>Cobalt</subject><subject>Colorimetry</subject><subject>Fluorescence</subject><subject>Manganese</subject><subject>Medical imaging</subject><subject>Original Article</subject><subject>Rhodamine</subject><subject>Silver</subject><subject>Tin</subject><issn>1053-0509</issn><issn>1573-4994</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxDAYhYsoOI6-gKuAG0GqSZvrshRHhQHBy04IaZvMdGgTTVrBnY_gM_okZqwguHBx-P_Fdw6HkyTHCJ4jCNlFQJALksIMRbEsfjvJDBGWp1gIvBt_SPIUEij2k4MQNhBCwTGfJU8FuFu7RvWt1Z_vH5UKugGLbnReh1rbAZRr3bvGhbbXg_bAOA-KMT8DrQXFy6jdGMC968ahdRYo24Bl-9raFSh114XDZM-oLuijnztPHheXD-V1ury9uimLZVpnPBtSYxA1FDPKUUMqQzBWgqCKUUGhUVWmUMPritaUKcNY3ugKCVZDQQzjOsM8nyenU-6zd7FTGGTfxvZdp-y2oMxIjimiURE9-YNu3OhtbBcpjDihCLNIZRNVexeC10Y--7ZX_k0iKLeDy2lwGQeX34NLGE35ZAoRtivtf6P_cX0BS7SDQw</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Pitsanuwong, Chariwat</creator><creator>Boonwan, Juthamanee</creator><creator>Chomngam, Sinchai</creator><creator>Wechakorn, Kanokorn</creator><creator>Kanjanasirirat, Phongthon</creator><creator>Pewkliang, Yongyut</creator><creator>Borwornpinyo, Suparerk</creator><creator>Kongsaeree, Palangpon</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2689-9651</orcidid></search><sort><creationdate>20210701</creationdate><title>A Rhodamine‐based Fluorescent Chemodosimeter for Au3+ in Aqueous Solution and Living Cells</title><author>Pitsanuwong, Chariwat ; Boonwan, Juthamanee ; Chomngam, Sinchai ; Wechakorn, Kanokorn ; Kanjanasirirat, Phongthon ; Pewkliang, Yongyut ; Borwornpinyo, Suparerk ; Kongsaeree, Palangpon</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c282t-ff16f647681d5bf544a951b76960fab2a1d8cb6c67af773deb197c095f78e2483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical Chemistry</topic><topic>Aqueous solutions</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Calcium ions</topic><topic>Cerium</topic><topic>Chemical sensors</topic><topic>Chemoreceptors</topic><topic>Cobalt</topic><topic>Colorimetry</topic><topic>Fluorescence</topic><topic>Manganese</topic><topic>Medical imaging</topic><topic>Original Article</topic><topic>Rhodamine</topic><topic>Silver</topic><topic>Tin</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pitsanuwong, Chariwat</creatorcontrib><creatorcontrib>Boonwan, Juthamanee</creatorcontrib><creatorcontrib>Chomngam, Sinchai</creatorcontrib><creatorcontrib>Wechakorn, Kanokorn</creatorcontrib><creatorcontrib>Kanjanasirirat, Phongthon</creatorcontrib><creatorcontrib>Pewkliang, Yongyut</creatorcontrib><creatorcontrib>Borwornpinyo, Suparerk</creatorcontrib><creatorcontrib>Kongsaeree, Palangpon</creatorcontrib><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pitsanuwong, Chariwat</au><au>Boonwan, Juthamanee</au><au>Chomngam, Sinchai</au><au>Wechakorn, Kanokorn</au><au>Kanjanasirirat, Phongthon</au><au>Pewkliang, Yongyut</au><au>Borwornpinyo, Suparerk</au><au>Kongsaeree, Palangpon</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Rhodamine‐based Fluorescent Chemodosimeter for Au3+ in Aqueous Solution and Living Cells</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>31</volume><issue>4</issue><spage>1211</spage><epage>1218</epage><pages>1211-1218</pages><issn>1053-0509</issn><issn>1573-4994</issn><eissn>1573-4994</eissn><abstract>A highly selective rhodamine hydrazide-based fluorescent chemosensor for Au
3+
detection was developed. The aqueous solution of rhodamine
N
-hydroxysemicarbazide (
RHS
), in the presence of Au
3+
, exhibited a significant 55-fold turn-on fluorescence response at 591 nm and a colorimetric change from colorless to pink. Other interested ions including Li
+
, Na
+
, K
+
, Cs
+
, Mg
2+
, Ca
2+
, Ba
2+
, Pb
2+
, Mn
2+
, Co
2+
, Ni
2+
, Ag
+
, Cd
2+
, Cu
2+
, Hg
2+
, Zn
2+
, Sn
2+
, Fe
2+
, Fe
3+
, Cr
3+
, Ce
3+
did not induce any distinct color/spectral changes. The irreversible detection mechanism occurred via Au
3+
-promoted 5-
exo
-
trig
ring closure to yield 1,3,4-oxadiazole-2-one product. The
RHS
probe is non-responsive to other biologically relevant metal ions and the limit of detection for Au
3+
was calculated to be 0.5 µM with a linear range of 0 to 90 µM. Fluorescence bioimaging of Au
3+
in HepG2 cells was also successfully demonstrated.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10895-021-02725-0</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-2689-9651</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1053-0509 |
| ispartof | Journal of fluorescence, 2021-07, Vol.31 (4), p.1211-1218 |
| issn | 1053-0509 1573-4994 1573-4994 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2534616461 |
| source | Springer Nature |
| subjects | Analytical Chemistry Aqueous solutions Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Calcium ions Cerium Chemical sensors Chemoreceptors Cobalt Colorimetry Fluorescence Manganese Medical imaging Original Article Rhodamine Silver Tin |
| title | A Rhodamine‐based Fluorescent Chemodosimeter for Au3+ in Aqueous Solution and Living Cells |
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