Polymerization of 4-vinyl biphenyl at advanced degrees of conversion

The bulk self-initiated polymerization kinetics, assuming total conversion, of the 4-vinyl biphenyl was determined by differential thermal analysis (DTA) in the temperature range 463-533K. Likewise, the overall activation energy, E sub A , and the polymerization enthalpies involved in the process ha...

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Bibliographic Details
Published in:Polymer bulletin (Berlin, Germany) Germany), 1989-12, Vol.22 (5-6), p.505-511
Main Authors: KATIME, I. A, NUNO, T
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Summary:The bulk self-initiated polymerization kinetics, assuming total conversion, of the 4-vinyl biphenyl was determined by differential thermal analysis (DTA) in the temperature range 463-533K. Likewise, the overall activation energy, E sub A , and the polymerization enthalpies involved in the process have been calculated, as well as the overall rate constants and the reaction order with respect to the monomer concentration. Graphs. 12 ref.--AA
ISSN:0170-0839
1436-2449
DOI:10.1007/BF00718926