Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal ‐Organic Frameworks Incorporating Ru(2,2′‐bpy)3 photosensitizer

Three isostructural lanthanide metal‐organic frameworks (Ln‐MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good co...

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Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2021-08, Vol.16 (15), p.2031-2034
Main Authors: Zhang, Xiaobang, Wei, Xiaomei, Huang, Sheng‐Li, Yang, Guo‐Yu
Format: Article
Language:English
Subjects:
Chemistry
Oxidation
Photocatalysis
Rare-earth metal-organic frameworks
Ru(N^N)3 photosensitizer
Selectivity
sulfide oxidation
Sulfides
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Summary:Three isostructural lanthanide metal‐organic frameworks (Ln‐MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N)3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity. Three isostructural frameworks were synthesized with Ln6 cluster and Ru(NN)3 photosensitizer, and they exhibited the capability of highly selective photocatalytic oxidation of sulfides.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.202100482