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Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes
Heptanuclear palladium clusters with six palladium atoms in a planar arrangement were obtained from the reaction of [Pd(CN t Bu) 2 ] 3 with Ph-substituted cyclotetrasilane or cyclopentasilane via the migration of a phenyl group. The molecular structures of these clusters as well as those of two poss...
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| Published in: | Chemical communications (Cambridge, England) England), 2021-08, Vol.57 (62), p.7649-7652 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c380t-3639cc09ee1b8dbec554acc85b9e18fab94c11452ae1dbda9bab46ce60f41c23 |
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| cites | cdi_FETCH-LOGICAL-c380t-3639cc09ee1b8dbec554acc85b9e18fab94c11452ae1dbda9bab46ce60f41c23 |
| container_end_page | 7652 |
| container_issue | 62 |
| container_start_page | 7649 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 57 |
| creator | Shimamoto, Kento Sunada, Yusuke |
| description | Heptanuclear palladium clusters with six palladium atoms in a planar arrangement were obtained from the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclotetrasilane or cyclopentasilane
via
the migration of a phenyl group. The molecular structures of these clusters as well as those of two possible intermediates were determined by single-crystal X-ray diffraction analyses.
Heptanuclear palladium clusters were synthesized
via
the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclooligosilanes. The generation of the SiPh moiety upon migration of a Ph group is the key to assembling the seven palladium atoms effectively. |
| doi_str_mv | 10.1039/d1cc02682h |
| format | article |
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t
Bu)
2
]
3
with Ph-substituted cyclotetrasilane or cyclopentasilane
via
the migration of a phenyl group. The molecular structures of these clusters as well as those of two possible intermediates were determined by single-crystal X-ray diffraction analyses.
Heptanuclear palladium clusters were synthesized
via
the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclooligosilanes. The generation of the SiPh moiety upon migration of a Ph group is the key to assembling the seven palladium atoms effectively.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc02682h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Clusters ; Crystallography ; Crystals ; Molecular structure ; Palladium ; Single crystals</subject><ispartof>Chemical communications (Cambridge, England), 2021-08, Vol.57 (62), p.7649-7652</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c380t-3639cc09ee1b8dbec554acc85b9e18fab94c11452ae1dbda9bab46ce60f41c23</citedby><cites>FETCH-LOGICAL-c380t-3639cc09ee1b8dbec554acc85b9e18fab94c11452ae1dbda9bab46ce60f41c23</cites><orcidid>0000-0002-8954-181X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Shimamoto, Kento</creatorcontrib><creatorcontrib>Sunada, Yusuke</creatorcontrib><title>Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes</title><title>Chemical communications (Cambridge, England)</title><description>Heptanuclear palladium clusters with six palladium atoms in a planar arrangement were obtained from the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclotetrasilane or cyclopentasilane
via
the migration of a phenyl group. The molecular structures of these clusters as well as those of two possible intermediates were determined by single-crystal X-ray diffraction analyses.
Heptanuclear palladium clusters were synthesized
via
the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclooligosilanes. The generation of the SiPh moiety upon migration of a Ph group is the key to assembling the seven palladium atoms effectively.</description><subject>Clusters</subject><subject>Crystallography</subject><subject>Crystals</subject><subject>Molecular structure</subject><subject>Palladium</subject><subject>Single crystals</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpd0U1LxDAQBuAgCq6rF-9CwIsI1aRJ2uYo68cKi3rYg7eSptNulmxTkxbsv7d1RcFcJodnhpcZhM4puaGEyduSak3iJIs3B2hGWcIjwbP3w-kvZJQyLo7RSQhbMj4qshmCl15bUN50A4bPVjXBuAabBr-VWNs-dOAD7rypa_BQ4mLA3QbwztRedZN0FVa43UAzWFx717dTrx60dc6a2gVjVQPhFB1VygY4-6lztH58WC-W0er16Xlxt4o0y0gXsYTJMb8EoEVWFqCF4ErrTBQSaFapQnJNKRexAloWpZKFKniiISEVpzpmc3S1H9t699FD6PKdCRrslMH1IY-FoDFJpExHevmPbl3vmzHcpFKeEpGRUV3vlfYuBA9V3nqzU37IKcmnhef3dLH4XvhyxBd77IP-dX8HYV_NhH75</recordid><startdate>20210803</startdate><enddate>20210803</enddate><creator>Shimamoto, Kento</creator><creator>Sunada, Yusuke</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8954-181X</orcidid></search><sort><creationdate>20210803</creationdate><title>Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes</title><author>Shimamoto, Kento ; Sunada, Yusuke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-3639cc09ee1b8dbec554acc85b9e18fab94c11452ae1dbda9bab46ce60f41c23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Clusters</topic><topic>Crystallography</topic><topic>Crystals</topic><topic>Molecular structure</topic><topic>Palladium</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shimamoto, Kento</creatorcontrib><creatorcontrib>Sunada, Yusuke</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shimamoto, Kento</au><au>Sunada, Yusuke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-08-03</date><risdate>2021</risdate><volume>57</volume><issue>62</issue><spage>7649</spage><epage>7652</epage><pages>7649-7652</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Heptanuclear palladium clusters with six palladium atoms in a planar arrangement were obtained from the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclotetrasilane or cyclopentasilane
via
the migration of a phenyl group. The molecular structures of these clusters as well as those of two possible intermediates were determined by single-crystal X-ray diffraction analyses.
Heptanuclear palladium clusters were synthesized
via
the reaction of [Pd(CN
t
Bu)
2
]
3
with Ph-substituted cyclooligosilanes. The generation of the SiPh moiety upon migration of a Ph group is the key to assembling the seven palladium atoms effectively.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1cc02682h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-8954-181X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-08, Vol.57 (62), p.7649-7652 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2551206997 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Clusters Crystallography Crystals Molecular structure Palladium Single crystals |
| title | Nuclearity expansion in Pd clusters triggered by the migration of a phenyl group in cyclooligosilanes |
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