Legacy and emerging poly- and perfluorochemicals in seawater and sediment from East China Sea

Following the global phase out of perfluorooctane sulfate (PFOS), chlorinated polyfluoroalkyl ether sulfonates (Cl-PFAESs) and p-perfluorous nonenoxybenzenesulfonate (PFNOBS) have emerged as novel PFOS substitutes. However, until now, limited data is available on their occurrence and environmental b...

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Published in:The Science of the total environment 2021-11, Vol.797, p.149052-149052, Article 149052
Main Authors: Hu, Hongmei, Zhang, Yingying, Zhao, Nan, Xie, Jiahui, Zhou, Yanqiu, Zhao, Meirong, Jin, Hangbiao
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Language:English
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6:2 Cl-PFAES
PFNOBS
PFOA
Seawater
Sediment
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container_title The Science of the total environment
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creator Hu, Hongmei
Zhang, Yingying
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description Following the global phase out of perfluorooctane sulfate (PFOS), chlorinated polyfluoroalkyl ether sulfonates (Cl-PFAESs) and p-perfluorous nonenoxybenzenesulfonate (PFNOBS) have emerged as novel PFOS substitutes. However, until now, limited data is available on their occurrence and environmental behaviors in the marine environment. Here, seawater and sediment samples were collected from East China Sea and analyzed for Cl-PFAESs, PFNOBS, and perfluoroalkyl acids (PFAAs; including their branched isomers) to investigate their concentrations, potential sources, and sediment-seawater partitioning behaviors. Perfluorooctanoate (PFOA) and PFOS were consistently the predominant PFAAs in seawaters and sediments. Branched PFOA and PFOS isomers were consistently much less frequently detected in sediments than that in seawaters. Linear PFOA contributed 92–95% of total PFOA in seawaters, suggesting the great contribution of telomerization PFOA. 6:2 Cl-PFAES was detected in all seawaters (concentration, 0.58–47 pg/L) and in the majority of sediments (
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However, until now, limited data is available on their occurrence and environmental behaviors in the marine environment. Here, seawater and sediment samples were collected from East China Sea and analyzed for Cl-PFAESs, PFNOBS, and perfluoroalkyl acids (PFAAs; including their branched isomers) to investigate their concentrations, potential sources, and sediment-seawater partitioning behaviors. Perfluorooctanoate (PFOA) and PFOS were consistently the predominant PFAAs in seawaters and sediments. Branched PFOA and PFOS isomers were consistently much less frequently detected in sediments than that in seawaters. Linear PFOA contributed 92–95% of total PFOA in seawaters, suggesting the great contribution of telomerization PFOA. 6:2 Cl-PFAES was detected in all seawaters (concentration, 0.58–47 pg/L) and in the majority of sediments (&lt;LOD–28 pg/g). PFNOBS was observed in 46% of seawater samples (concentration, &lt;LOD–5.2 pg/L) and 66% of sediment samples (&lt;LOD–1.7 pg/g). Spatial distribution trend suggested the riverine input as an important source of PFAAs and 6:2 Cl-PFAES in this sampling area. 6:2 Cl-PFAES (log Koc, 2.6 ± 0.36) and PFNOBS (2.7 ± 0.33) had comparable mean log-transformed sediment-seawater partitioning coefficients (log Koc) to PFOA (2.5 ± 0.32) or PFOS (2.8 ± 0.49), indicating their long-range transport potential in global oceans with ocean currents. Overall, this study provides the first data on occurrence and partitioning behaviors of 6:2 Cl-PFAES and PFNOBS in the marine environment. 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However, until now, limited data is available on their occurrence and environmental behaviors in the marine environment. Here, seawater and sediment samples were collected from East China Sea and analyzed for Cl-PFAESs, PFNOBS, and perfluoroalkyl acids (PFAAs; including their branched isomers) to investigate their concentrations, potential sources, and sediment-seawater partitioning behaviors. Perfluorooctanoate (PFOA) and PFOS were consistently the predominant PFAAs in seawaters and sediments. Branched PFOA and PFOS isomers were consistently much less frequently detected in sediments than that in seawaters. Linear PFOA contributed 92–95% of total PFOA in seawaters, suggesting the great contribution of telomerization PFOA. 6:2 Cl-PFAES was detected in all seawaters (concentration, 0.58–47 pg/L) and in the majority of sediments (&lt;LOD–28 pg/g). PFNOBS was observed in 46% of seawater samples (concentration, &lt;LOD–5.2 pg/L) and 66% of sediment samples (&lt;LOD–1.7 pg/g). Spatial distribution trend suggested the riverine input as an important source of PFAAs and 6:2 Cl-PFAES in this sampling area. 6:2 Cl-PFAES (log Koc, 2.6 ± 0.36) and PFNOBS (2.7 ± 0.33) had comparable mean log-transformed sediment-seawater partitioning coefficients (log Koc) to PFOA (2.5 ± 0.32) or PFOS (2.8 ± 0.49), indicating their long-range transport potential in global oceans with ocean currents. Overall, this study provides the first data on occurrence and partitioning behaviors of 6:2 Cl-PFAES and PFNOBS in the marine environment. 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However, until now, limited data is available on their occurrence and environmental behaviors in the marine environment. Here, seawater and sediment samples were collected from East China Sea and analyzed for Cl-PFAESs, PFNOBS, and perfluoroalkyl acids (PFAAs; including their branched isomers) to investigate their concentrations, potential sources, and sediment-seawater partitioning behaviors. Perfluorooctanoate (PFOA) and PFOS were consistently the predominant PFAAs in seawaters and sediments. Branched PFOA and PFOS isomers were consistently much less frequently detected in sediments than that in seawaters. Linear PFOA contributed 92–95% of total PFOA in seawaters, suggesting the great contribution of telomerization PFOA. 6:2 Cl-PFAES was detected in all seawaters (concentration, 0.58–47 pg/L) and in the majority of sediments (&lt;LOD–28 pg/g). PFNOBS was observed in 46% of seawater samples (concentration, &lt;LOD–5.2 pg/L) and 66% of sediment samples (&lt;LOD–1.7 pg/g). Spatial distribution trend suggested the riverine input as an important source of PFAAs and 6:2 Cl-PFAES in this sampling area. 6:2 Cl-PFAES (log Koc, 2.6 ± 0.36) and PFNOBS (2.7 ± 0.33) had comparable mean log-transformed sediment-seawater partitioning coefficients (log Koc) to PFOA (2.5 ± 0.32) or PFOS (2.8 ± 0.49), indicating their long-range transport potential in global oceans with ocean currents. Overall, this study provides the first data on occurrence and partitioning behaviors of 6:2 Cl-PFAES and PFNOBS in the marine environment. [Display omitted] •PFNOBS was first detected in seawater and sediment from East China Sea.•Linear PFOA accounted for 92–95% of total PFOA in seawater samples.•PFOA and PFOS isomers were first examined in Chinese marine environment.•6:2 Cl-PFAES and PFNOBS had comparable mean log Koc values to PFOA and PFOS.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.scitotenv.2021.149052</doi><tpages>1</tpages></addata></record>
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subjects 6:2 Cl-PFAES
PFNOBS
PFOA
Seawater
Sediment
title Legacy and emerging poly- and perfluorochemicals in seawater and sediment from East China Sea
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