Transient migration behavior of VOC vapor in layered unsaturated soils subjected to multiple time-dependent point pollution sources: Analytical study

• Published in: The Science of the total environment 2022-02, Vol.806, p.150370-150370, Article 150370
• Main Authors: Ding, Xiang-Hong, Feng, Shi-Jin, Zheng, Qi-Teng, Peng, Chun-Hui, Zhu, Zhang-Wen, Yang, Chun-Bai-Xue
• Format: Article
• Language: English
• Subjects: Biodegradation; Layered unsaturated soil; Multiple point sources; Time-dependent release; Two-dimensional migration of VOC vapor
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2021.150370

Predicting the migration behavior of volatile organic compounds (VOCs) vapor is essential for the remediation of subsurface contamination such as soil vapor extraction. Previous analytical prediction models of VOCs migration are mostly limited to constant-concentration nonpoint sources in homogeneous soil. Thus, this study presents a novel analytical model for two-dimensional transport of VOCs vapor subjected to multiple time-dependent point sources involving transient diffusion, sorption and degradation in layered unsaturated soils. Two representative time-dependent sources, i.e., an instantaneous source and a finite pulse source, are used to describe the short-term and long-term leakage. Results reveal that soil heterogeneity can cause pollution accumulation, especially in low-diffusivity capillary fringe. The assumption of an equivalent plane source from multiple point sources would significantly overestimate the vapor concentration and the contaminated range. The previous single point source model is no longer inapplicable when the relative distance and/or the release interval between sources is small, giving a strong interaction between multiple sources. Moreover, a faster vapor degradation rate or a higher groundwater level will reduce the area of vapor plume linearly. Hence, close attention should be paid to the time-variation characteristics of multiple sources, the vapor degradation and the groundwater level fluctuation in practice to facilitate soil remediation. The proposed model is a promising tool for addressing the above issue. [Display omitted] •A novel prediction model for VOC vapor migration in heterogeneous unsaturated soil•Time-dependent release characteristic and interaction of point pollution sources•Contaminant degradation and water-level fluctuation•An analytical method for estimating the potential risk assessment of VOC vapor•Some advice for the remediation of subsurface VOC vapor