Al3+ solvation in solutions of aluminum nitrate in a protic ionic liquid: Nuclear magnetic resonance verification of the solvation shell composition

The closest environment of Al3+ cations was analyzed in detail in solutions of aluminum nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N nuclear magnetic resonance (NMR) spectra. For Al (NO3)3–EAN mixtures with different water content, a quantitative anal...

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Published in:Magnetic resonance in chemistry 2022-02, Vol.60 (2), p.221-225
Main Authors: Matveev, Vladimir V., Ievlev, Alexandr, Šoltésová, Mária, Štěpánková, Helena, Lähderanta, Erkki, Varela, Luis M.
Format: Article
Language:English
Subjects:
14N
27Al
Aluminum
Aluminum nitrate
Ammonium nitrate
aqua complex
Cations
Composition
ionic liquid
Ionic liquids
Ions
Moisture content
Nitrates
NMR
Nuclear magnetic resonance
Solvation
solvation shell
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container_end_page 225
container_issue 2
container_start_page 221
container_title Magnetic resonance in chemistry
container_volume 60
creator Matveev, Vladimir V.
Ievlev, Alexandr
Šoltésová, Mária
Štěpánková, Helena
Lähderanta, Erkki
Varela, Luis M.
description The closest environment of Al3+ cations was analyzed in detail in solutions of aluminum nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N nuclear magnetic resonance (NMR) spectra. For Al (NO3)3–EAN mixtures with different water content, a quantitative analysis of the integral intensities of the 1H and 14N signals was carried out and the composition of the first solvation shell of the aluminum cation was refined.
doi_str_mv 10.1002/mrc.5220
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subjects 14N
27Al
Aluminum
Aluminum nitrate
Ammonium nitrate
aqua complex
Cations
Composition
ionic liquid
Ionic liquids
Ions
Moisture content
Nitrates
NMR
Nuclear magnetic resonance
Solvation
solvation shell
title Al3+ solvation in solutions of aluminum nitrate in a protic ionic liquid: Nuclear magnetic resonance verification of the solvation shell composition
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