Highly uniform platanus fruit-like CuCo2S4 microspheres as an electrode material for high performance lithium-ion batteries and supercapacitors

• Published in: Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.50 (37), p.13042-13051
• Main Authors: Guan, Baole, Yu-Shen, Zhao, Zhang, Nan, Jun-Hong, Zhang, Sun, Ting, Ting-Feng, Yi
• Format: Article
• Language: English
• Subjects: Anodes; Bimetals; Electrode materials; Flux density; Lithium; Lithium-ion batteries; Microspheres; Rechargeable batteries; Sulfidation; Supercapacitors; Synergistic effect
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d1dt02306c

Platanus fruit-like CuCo2S4 microspheres were fabricated by using a facile hydrothermal method followed by a sulfidation process. As a lithium storage material, they deliver an outstanding initial specific capacity of 1119.3 mA h g−1 at 0.05 A g−1 and a high reversibility of 954 mA h g−1 over 200 cycles even at 1 A g−1. In addition, when applied in supercapacitors they display a superb specific capacitance of 824 F g−1 at 1 A g−1, even over 10 000 cycles and they can also maintain 75% retention at 5 A g−1 and exhibit good reversibility. Furthermore, an advanced asymmetric supercapacitor (ASC) exhibits an advantageous energy density of 36.67 W h kg−1 when the power density increases up to 750 W kg−1. Additionally, the assembled device can easily light a 1.5 V bulb for several minutes. The excellent performance of CuCo2S4 is due to the bimetallic synergistic effect and the unique platanus fruit-like microsphere architecture, which can limit the restacking of the structure and provide suitable voids. This excellent performance confirms that platanus fruit-like CuCo2S4 microspheres are a promising electrode material for energy storge. This work will provide a new strategy to prepare high-performance bimetallic sulfide anode materials by a facile method.