Loading…
Thermal evolution of NASICON type solid-state electrolytes with lithium at high temperature via in situ scanning electron microscopy
We present the thermal evolution of two NASICON-type ceramics namely LATP (Li 1+ x Al x Ti 2− x (PO 4 ) 3 ) and LAGP (Li 1+ x Al x Ge 2− x (PO 4 ) 3 ) by monitoring the electrode–electrolyte interfaces ( i.e. , Li/LATP and Li/LAGP) at temperatures up to 330 °C via in situ scanning electron microscop...
Saved in:
| Published in: | Chemical communications (Cambridge, England) England), 2021-10, Vol.57 (84), p.11076-11079 |
|---|---|
| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033 |
| container_end_page | 11079 |
| container_issue | 84 |
| container_start_page | 11076 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 57 |
| creator | Kaboli, Shirin Girard, Gabriel Zhu, Wen Gheorghe Nita, Alina Vijh, Ashok George, Chandramohan Trudeau, Michel L. Paolella, Andrea |
| description | We present the thermal evolution of two NASICON-type ceramics namely LATP (Li
1+
x
Al
x
Ti
2−
x
(PO
4
)
3
) and LAGP (Li
1+
x
Al
x
Ge
2−
x
(PO
4
)
3
) by monitoring the electrode–electrolyte interfaces (
i.e.
, Li/LATP and Li/LAGP) at temperatures up to 330 °C
via in situ
scanning electron microscopy, post-mortem energy-dispersive spectroscopy, and X-ray diffraction. Upon melting of Li and contacting electrolytes, LAGP decomposes completely to form Li based alloys, while LATP is partially decomposed without alloying. |
| doi_str_mv | 10.1039/d1cc04059f |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2580026343</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2583927406</sourcerecordid><originalsourceid>FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033</originalsourceid><addsrcrecordid>eNpdkU1LxDAQhosoqKsXf0HAiwjVfO42R6muCqIHFbyVbDrZzZI2NUlX9u4Pt_Xj4hxmhuHhZWbeLDsh-IJgJi9rojXmWEizkx0QNuW54MXb7tgLmc8YF_vZYYxrPAQRxUH2-bKC0CiHYONdn6xvkTfo8er5vnx6RGnbAYre2TqPSSVA4ECn4N02QUQfNq2QG5LtG6QSWtnlCiVoOggq9QHQxipkWxRt6lHUqm1tu_yTaFFjdfBR-257lO0Z5SIc_9ZJ9jq_eSnv8oen2_vy6iHXlNKUm0JQyvhiRlWtiNSgCqJ5QZk2UujFMKSFghksFDGUGWk4EfVUSl4P_xCYsUl29qPbBf_eQ0xVY6MG51QLvo8VFQXGdMr4iJ7-Q9e-D-2w3UgxSWccTwfq_IcaL4kBTNUF26iwrQiuRkOqa1KW34bM2RduEoAz</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2583927406</pqid></control><display><type>article</type><title>Thermal evolution of NASICON type solid-state electrolytes with lithium at high temperature via in situ scanning electron microscopy</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Kaboli, Shirin ; Girard, Gabriel ; Zhu, Wen ; Gheorghe Nita, Alina ; Vijh, Ashok ; George, Chandramohan ; Trudeau, Michel L. ; Paolella, Andrea</creator><creatorcontrib>Kaboli, Shirin ; Girard, Gabriel ; Zhu, Wen ; Gheorghe Nita, Alina ; Vijh, Ashok ; George, Chandramohan ; Trudeau, Michel L. ; Paolella, Andrea</creatorcontrib><description>We present the thermal evolution of two NASICON-type ceramics namely LATP (Li
1+
x
Al
x
Ti
2−
x
(PO
4
)
3
) and LAGP (Li
1+
x
Al
x
Ge
2−
x
(PO
4
)
3
) by monitoring the electrode–electrolyte interfaces (
i.e.
, Li/LATP and Li/LAGP) at temperatures up to 330 °C
via in situ
scanning electron microscopy, post-mortem energy-dispersive spectroscopy, and X-ray diffraction. Upon melting of Li and contacting electrolytes, LAGP decomposes completely to form Li based alloys, while LATP is partially decomposed without alloying.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc04059f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Decomposition ; Electrolytes ; High temperature ; Lithium base alloys ; Molten salt electrolytes ; Scanning electron microscopy ; Solid electrolytes ; Temperature ; Thermal evolution</subject><ispartof>Chemical communications (Cambridge, England), 2021-10, Vol.57 (84), p.11076-11079</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033</citedby><cites>FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033</cites><orcidid>0000-0002-4915-0064</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kaboli, Shirin</creatorcontrib><creatorcontrib>Girard, Gabriel</creatorcontrib><creatorcontrib>Zhu, Wen</creatorcontrib><creatorcontrib>Gheorghe Nita, Alina</creatorcontrib><creatorcontrib>Vijh, Ashok</creatorcontrib><creatorcontrib>George, Chandramohan</creatorcontrib><creatorcontrib>Trudeau, Michel L.</creatorcontrib><creatorcontrib>Paolella, Andrea</creatorcontrib><title>Thermal evolution of NASICON type solid-state electrolytes with lithium at high temperature via in situ scanning electron microscopy</title><title>Chemical communications (Cambridge, England)</title><description>We present the thermal evolution of two NASICON-type ceramics namely LATP (Li
1+
x
Al
x
Ti
2−
x
(PO
4
)
3
) and LAGP (Li
1+
x
Al
x
Ge
2−
x
(PO
4
)
3
) by monitoring the electrode–electrolyte interfaces (
i.e.
, Li/LATP and Li/LAGP) at temperatures up to 330 °C
via in situ
scanning electron microscopy, post-mortem energy-dispersive spectroscopy, and X-ray diffraction. Upon melting of Li and contacting electrolytes, LAGP decomposes completely to form Li based alloys, while LATP is partially decomposed without alloying.</description><subject>Decomposition</subject><subject>Electrolytes</subject><subject>High temperature</subject><subject>Lithium base alloys</subject><subject>Molten salt electrolytes</subject><subject>Scanning electron microscopy</subject><subject>Solid electrolytes</subject><subject>Temperature</subject><subject>Thermal evolution</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkU1LxDAQhosoqKsXf0HAiwjVfO42R6muCqIHFbyVbDrZzZI2NUlX9u4Pt_Xj4hxmhuHhZWbeLDsh-IJgJi9rojXmWEizkx0QNuW54MXb7tgLmc8YF_vZYYxrPAQRxUH2-bKC0CiHYONdn6xvkTfo8er5vnx6RGnbAYre2TqPSSVA4ECn4N02QUQfNq2QG5LtG6QSWtnlCiVoOggq9QHQxipkWxRt6lHUqm1tu_yTaFFjdfBR-257lO0Z5SIc_9ZJ9jq_eSnv8oen2_vy6iHXlNKUm0JQyvhiRlWtiNSgCqJ5QZk2UujFMKSFghksFDGUGWk4EfVUSl4P_xCYsUl29qPbBf_eQ0xVY6MG51QLvo8VFQXGdMr4iJ7-Q9e-D-2w3UgxSWccTwfq_IcaL4kBTNUF26iwrQiuRkOqa1KW34bM2RduEoAz</recordid><startdate>20211021</startdate><enddate>20211021</enddate><creator>Kaboli, Shirin</creator><creator>Girard, Gabriel</creator><creator>Zhu, Wen</creator><creator>Gheorghe Nita, Alina</creator><creator>Vijh, Ashok</creator><creator>George, Chandramohan</creator><creator>Trudeau, Michel L.</creator><creator>Paolella, Andrea</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-4915-0064</orcidid></search><sort><creationdate>20211021</creationdate><title>Thermal evolution of NASICON type solid-state electrolytes with lithium at high temperature via in situ scanning electron microscopy</title><author>Kaboli, Shirin ; Girard, Gabriel ; Zhu, Wen ; Gheorghe Nita, Alina ; Vijh, Ashok ; George, Chandramohan ; Trudeau, Michel L. ; Paolella, Andrea</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Decomposition</topic><topic>Electrolytes</topic><topic>High temperature</topic><topic>Lithium base alloys</topic><topic>Molten salt electrolytes</topic><topic>Scanning electron microscopy</topic><topic>Solid electrolytes</topic><topic>Temperature</topic><topic>Thermal evolution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kaboli, Shirin</creatorcontrib><creatorcontrib>Girard, Gabriel</creatorcontrib><creatorcontrib>Zhu, Wen</creatorcontrib><creatorcontrib>Gheorghe Nita, Alina</creatorcontrib><creatorcontrib>Vijh, Ashok</creatorcontrib><creatorcontrib>George, Chandramohan</creatorcontrib><creatorcontrib>Trudeau, Michel L.</creatorcontrib><creatorcontrib>Paolella, Andrea</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kaboli, Shirin</au><au>Girard, Gabriel</au><au>Zhu, Wen</au><au>Gheorghe Nita, Alina</au><au>Vijh, Ashok</au><au>George, Chandramohan</au><au>Trudeau, Michel L.</au><au>Paolella, Andrea</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal evolution of NASICON type solid-state electrolytes with lithium at high temperature via in situ scanning electron microscopy</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-10-21</date><risdate>2021</risdate><volume>57</volume><issue>84</issue><spage>11076</spage><epage>11079</epage><pages>11076-11079</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We present the thermal evolution of two NASICON-type ceramics namely LATP (Li
1+
x
Al
x
Ti
2−
x
(PO
4
)
3
) and LAGP (Li
1+
x
Al
x
Ge
2−
x
(PO
4
)
3
) by monitoring the electrode–electrolyte interfaces (
i.e.
, Li/LATP and Li/LAGP) at temperatures up to 330 °C
via in situ
scanning electron microscopy, post-mortem energy-dispersive spectroscopy, and X-ray diffraction. Upon melting of Li and contacting electrolytes, LAGP decomposes completely to form Li based alloys, while LATP is partially decomposed without alloying.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1cc04059f</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-4915-0064</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-10, Vol.57 (84), p.11076-11079 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2580026343 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Decomposition Electrolytes High temperature Lithium base alloys Molten salt electrolytes Scanning electron microscopy Solid electrolytes Temperature Thermal evolution |
| title | Thermal evolution of NASICON type solid-state electrolytes with lithium at high temperature via in situ scanning electron microscopy |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T12%3A18%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermal%20evolution%20of%20NASICON%20type%20solid-state%20electrolytes%20with%20lithium%20at%20high%20temperature%20via%20in%20situ%20scanning%20electron%20microscopy&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Kaboli,%20Shirin&rft.date=2021-10-21&rft.volume=57&rft.issue=84&rft.spage=11076&rft.epage=11079&rft.pages=11076-11079&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d1cc04059f&rft_dat=%3Cproquest_cross%3E2583927406%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c222t-f852234b72ada19cea81c4823cf95cbada28ae7eba1f23f9f415d6994d59f5033%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2583927406&rft_id=info:pmid/&rfr_iscdi=true |