First-Row d‑Block Element-Catalyzed Carbon–Boron Bond Formation and Related Processes

Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented reactivity. The transformation of the carbon–boron bond into a carbon–X (X = C, N, and O) bond in a stereocontrolled fashion has become invaluable...

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Bibliographic Details
Published in:Chemical reviews 2021-11, Vol.121 (21), p.13238-13341
Main Authors: Bose, Shubhankar Kumar, Mao, Lujia, Kuehn, Laura, Radius, Udo, Nekvinda, Jan, Santos, Webster L, Westcott, Stephen A, Steel, Patrick G, Marder, Todd B
Format: Article
Language:English
Subjects:
Boron
Boron - chemistry
Carbon
Carbon - chemistry
Catalysis
Catalysts
Chemistry
Materials science
Metals
Natural products
Organic chemistry
Reagents
State-of-the-art reviews
Transition Elements
Transition metals
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Summary:Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented reactivity. The transformation of the carbon–boron bond into a carbon–X (X = C, N, and O) bond in a stereocontrolled fashion has become invaluable in medicinal chemistry, agrochemistry, and natural products chemistry as well as materials science. Over the past decade, first-row d-block transition metals have become increasingly widely used as catalysts for the formation of a carbon–boron bond, a transformation traditionally catalyzed by expensive precious metals. This recent focus on alternative transition metals has enabled growth in fundamental methods in organoboron chemistry. This review surveys the current state-of-the-art in the use of first-row d-block element-based catalysts for the formation of carbon–boron bonds.
ISSN:0009-2665
1520-6890
DOI:10.1021/acs.chemrev.1c00255