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A new treatment for calculating activities from phase diagrams containing solid solution

A new treatment for calculating activities and activity coefficients of components from phase diagram at a fixed temperature is presented for a binary system involving the liquid and solid solution equilibrium, in which the Richardson's assumption, ΔHi ΔS E i is approximately equal to 3000, has...

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Bibliographic Details
Published in:Calphad 1990-07, Vol.14 (3), p.275-282
Main Author: Chou, K-C
Format: Article
Language:English
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Summary:A new treatment for calculating activities and activity coefficients of components from phase diagram at a fixed temperature is presented for a binary system involving the liquid and solid solution equilibrium, in which the Richardson's assumption, ΔHi ΔS E i is approximately equal to 3000, has been adopted. The application to the Cu-Ni system shows that this treatment is efficient.
ISSN:0364-5916
1873-2984
DOI:10.1016/0364-5916(90)90027-W