A low-cost photo-evaporation inorganic membrane preparation and treatment of the simulated high salinity radioactive waste water

• Published in: Journal of hazardous materials 2022-02, Vol.424 (Pt B), p.127433-127433, Article 127433
• Main Authors: Deng, Xingfa, Ge, Yuanyuan, He, Yan, Cui, Xuemin
• Format: Article
• Language: English
• Subjects: Desalination; Geopolymer; In situ self-reduced; Liquid radioactive waste; Radioactive Waste; Salinity; Sunlight; Waste Water; Water Purification
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2021.127433

Solar-driven desalination is an energy-saving and environmentally benign wastewater treatment technology. A method of in situ self-reduction of graphene oxide (rGO) by cheap geopolymer was introduced, and a photo evaporation membrane device (rGOPGC) for treatment of the simulated high salt liquid radioactive waste (HSLRW) was prepared in the present study. Compared with other rGO based photo evaporation membrane materials, geopolymer matrix has the advantages of low cost, reductant free, simple preparation process and mild conditions. After desalination of simulated seawater, the concentrations of Na+, K+, Ca2+ and Mg2+ ions reached the WHO standard, and the removal rates of radioactive I-, Cs+ and Sr2+ in the simulated high salinity wastewater reached 99.62%, 99.71% and 99.99% respectively; The evaporation rate of rGOPGC remained stable at 1.5 kg/m2/h after 16 cycles in high salinity environment. There was no obvious salt accumulation on the upper surface of the device, indicating its high stability. Furthermore, the evaporation performance at high temperature near the nuclear power plant (NPP) waste water was simulated and tested. Under one solar intensity and 35 °C ambient temperature, the evaporation rate of 1.75 kg/m2/h and the evaporation efficiency of 98.51% were achieved. The results indicated that the rGOPGC device is potential in the concentration evaluation of HSLRW. [Display omitted] •A low-cost reduced graphene oxide-porous inorganic membrane was prepared by foam geopolymer.•The evaporation rate of the photo-evaporation membrane can reach 1.75 kg/m2/h under irradiation of 1 sun.•After desalination of simulated seawater, the ion concentrations reached the WHO standard.•The removal rates of radioactive ion in high salinity wastewater can exceed 99%.