Unexpected exfoliation and activity of nano poly(tetrafluoroethylene) particles from magnetic stir bars: Discovery and implication

Magnetic stir bars are routinely used by most of researchers in the fields of chemistry, biology and environment etc. An incredible phenomenon, in which the magnetic stirring increased reaction rate by tens of times under ultrasound irradiation, impelled us to explore roles of magnetic stirring. Une...

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Bibliographic Details
Published in:Chemosphere (Oxford) 2022-03, Vol.291 (Pt 2), p.132797-132797, Article 132797
Main Authors: Wang, Yanfeng, Zhang, Jing, Pu, Liangtao, Cao, Miao, Dong, Shangshang, Vecitis, Chad D., Gao, Guandao
Format: Article
Language:English
Subjects:
Fluorocarbons
Magnetic Phenomena
Magnetic stir bar
Magnetics
Physical Phenomena
Piezocatalysis
Poly(tetrafluoroethylene)
Reactive oxygen species
Tribocatalysis
Ultrasound
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Summary:Magnetic stir bars are routinely used by most of researchers in the fields of chemistry, biology and environment etc. An incredible phenomenon, in which the magnetic stirring increased reaction rate by tens of times under ultrasound irradiation, impelled us to explore roles of magnetic stirring. Unexpectedly, the thimbleful nano PTFE particles, from shell of magnetic stir bar, were exfoliated during magnetic stirring and account for ultrahigh tribocatalytic and piezocatalytic activities under ultrasonic irradiation. Reactive oxygen species (ROS), such as hydroxyl radical (OH), superoxide radicals (O2−) and singlet oxygen (1O2) were generated in the present of PTFE under ultrasound irradiation, which is desired in the pollution control. The newly discovered PTFE activity, against the conventional wisdom that PTFE is inert, which also reminds the researchers that the trace amount of PTFE ground during magnetic stirring may inadvertently botch our experiments and introduce false positive results, especially involving routine magnetic stirring and ultrasound irradiation operation in laboratory. In addition, the safety and inertness of PTFE may require further review in PTFE-based commercial, industrial and biomedical settings. [Display omitted] •The thimbleful nano PTFE particles were exfoliated from magnetic stir bar during stirring.•Ultrasound can induce PTFE to generated strong aqueous reactive oxygen species.•The safety and inertness of PTFE may require further review.
ISSN:0045-6535
1879-1298
DOI:10.1016/j.chemosphere.2021.132797