In-situ growth of Co/Ni bimetallic organic frameworks on carbon spheres with catalytic ozonation performance for removal of bio-treated coking wastewater

• Published in: Chemosphere (Oxford) 2022-03, Vol.291 (Pt 2), p.132874-132874, Article 132874
• Main Authors: Pang, Zijun, Luo, Pei, Wei, Cong, Qin, Zhi, Wei, Tuo, Hu, Yun, Wu, Haizhen, Wei, Chaohai
• Format: Article
• Language: English
• Subjects: Bio-treated coking wastewater; Carbon; Catalysis; Catalytic ozonation; Co/ni-MOFs@CS; Coke; Levofloxacin; Metal organic framework; Ozone; Waste Water; Water Pollutants, Chemical - analysis
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2021.132874

The Co/Ni-MOFs@CS composite derived from Co/Ni bimetallic organic framework was synthesized and characterized. Compared with a single O3 system, the synergy between carbon sphere (CS) and metal organic frameworks (MOFs) improved the electron transfer efficiency and the formation rate of •OH. The coexistence of Co and Ni in various valence states might accelerate the cyclic process of Co(II)/Co(III) and Ni(II)/Ni(III), thereby improving the catalytic activity. Taking levofloxacin as a model pollutant, the mechanism of catalytic process was discussed, and the catalytic reaction was successfully applied to the removal of residual organics in bio-treated coking wastewater (BTCW). The removal rates of chemical oxygen demand (COD) and total organic carbon (TOC) in 60 min were 50.85%–53.71% and 39.98%–43.48%. From the perspective of UV absorption and 3D EEM, catalytic ozonation was more conducive to breaking the electronic protection of inert organic molecules such as heterocyclic compounds, and achieving higher efficiency of mineralization. It provides a new idea for catalytic ozonation technology of wastewater treatment in the future from theory, technology and application. [Display omitted] •The Co/Ni-MOFs@CS was successfully synthesized by hydrothermal method.•High specific surface areas and coexistence of multiple valence metals.•Strong nonselective oxidation capacity of OH was the mian factor for mineralization.•From the mineralization of single organic pollutant to the application of BTCW.