Evaluation of oil palm fiber biochar and activated biochar for sulphur dioxide adsorption

The emission of sulphur dioxide (SO2) gas from power plants and factories to the atmosphere has been an environmental challenge globally. Thus, there is a great interest to control the SO2 gas emission economically and effectively. This study aims to use and convert abundantly available oil palm fib...

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Bibliographic Details
Published in:The Science of the total environment 2022-01, Vol.805, p.150421-150421, Article 150421
Main Authors: Iberahim, Nursashabila, Sethupathi, Sumathi, Bashir, Mohammed J.K., Kanthasamy, Ramesh, Ahmad, Tanveer
Format: Article
Language:English
Subjects:
Activated biochar
Adsorption
Biochar
Oil palm fiber
Sulphur dioxide
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Summary:The emission of sulphur dioxide (SO2) gas from power plants and factories to the atmosphere has been an environmental challenge globally. Thus, there is a great interest to control the SO2 gas emission economically and effectively. This study aims to use and convert abundantly available oil palm fiber (OPF) biomass into an adsorbent to adsorb SO2 gas. The preparation of OPF biochar and activated biochar was optimised using the Response Surface Methodology (RSM) based on selected parameters (i.e., pyrolysis temperature, heating rate, holding time, activation temperature, activation time and CO2 flowrate). The best adsorbent was found to be the OPF activated biochar (OPFAB) compared to OPF biochar. OPFAB prepared at 753 °C for 73 min of activation time with 497 ml/min of CO2 flow yields the best adsorption capacity (33.09 mg/g) of SO2. Meanwhile, OPF pyrolysed at 450 °C of heating temperature, 12 °C/min of heating rate and 98 min of holding time yield adsorption capacity at 18.62 mg/g. Various characterisations were performed to investigate the properties and mechanism of the SO2 adsorption process. Thermal regeneration shows the possibilities for the spent adsorbent to be recycled. The findings imply OPFAB as a promising adsorbent for SO2 adsorption. [Display omitted] •Potential of palm oil fiber biomass as an adsorbent for SO2 gas•Activation of palm oil fiber biochar using CO2•Optimisation using response surface methodology and process study•High adsorption capacity of SO2 by palm oil fiber activated biochar with humidity•Thermal treatment for adsorbent regeneration
ISSN:0048-9697
1879-1026
DOI:10.1016/j.scitotenv.2021.150421