One-step preparation of cobalt phosphate at room temperature for effective photocatalytic H2 evolution

• Published in: Photochemical & photobiological sciences 2022-01, Vol.21 (1), p.49-57
• Main Authors: Liu, Xing, Lai, Hua, Li, Junhua, Peng, Gang, Zeng, Rongying
• Format: Article
• Language: English
• Subjects: Biochemistry; Biomaterials; Chemistry; Chemistry and Materials Science; Original Papers; Physical Chemistry; Plant Sciences
• ISSN: 1474-905X; 1474-9092
• DOI: 10.1007/s43630-021-00139-2

Cobalt phosphate materials were prepared in the present work in one step at room temperature using different raw materials and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and N 2 gas adsorption. Cobalt phosphates exhibit 3D flower-like structures, and the assembly of nanosheets (petals of the “flowers”) of cobalt phosphate prepared with sodium phosphate and cobalt acetate as raw materials (denoted as Co-P(A)) is more incompact than that of cobalt phosphate prepared with diammonium hydrogen phosphate and cobalt nitrate as raw materials (denoted as Co-P(B)) due to the former’s mildly basic environment. The cobalt phosphates show relatively high photocatalytic activity for H 2 evolution reaction (HER) in the presence of Eosin Y as a sensitizer in an aqueous triethanolamine solution. The activity of Co-P(A) (0.40 mmol h −1  g −1 ) exceeds that of Co-P(B) (0.19 mmol h −1  g −1 ), which can be attributed to a more dispersive nanosheet and larger BET-specific surface area of Co-P(A). The mechanisms of photocatalytic HER and the formation of flower-like Co 3 (PO 4 ) 2 were discussed. The present system comprising of only abundant elements contributes toward the development of cost-efficient solar HER to achieve sustainable development. Graphical abstract