Electrocatalysis degradation of coal tar wastewater using a novel hydrophobic benzalacetone modified lead dioxide electrode

• Published in: Chemosphere (Oxford) 2022-02, Vol.289, p.133014-133014, Article 133014
• Main Authors: Yu, Naichuan, Wei, Jingyu, Gu, Zhensheng, Sun, Hailong, Guo, Yong, Zong, Jun, Li, Xi, Ni, Pan, Han, Enshan
• Format: Article
• Language: English
• Subjects: Butanones; Coal Tar; Coal tar wastewater; Degradation mechanism; ECOSAR; Electrocatalytic; Electrodes; Hydrophobic and Hydrophilic Interactions; Lead; Lead dioxide electrodes; Oxidation-Reduction; Oxides; Phenol; Titanium; Waste Water; Water Pollutants, Chemical - analysis
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2021.133014

Coal tar wastewater is hard to degrade by traditional methods because of its toxic pollutant constituents and high concentration of aromatic hydrocarbons, especially phenolic substances. A new type of hydrophobic benzacetone modified PbO2 anode (BA-PbO2 electrodes) was used for the electrocatalytic treatment of coal tar wastewater in a continuous cycle reactor. The surface morphology, structure, valences of elements, hydrophobicity, hydroxyl radical (·OH) produced capacity, electrochemical properties and stability of BA-PbO2 electrodes were characterized by SEM (scanning electron microscopy), XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), contact angle, a fluorescence probe test, an electrochemical workstation and accelerated life test, respectively. The BA-PbO2 electrodes exhibited a compact structure and finely dispersed crystallize size of 4.6 nm. The optimum degradation conditions of coal tar wastewater were as follows: current density of 90 mA cm−2, electrode gap of 1 cm and temperature at 25 °C with flow velocity of 80 L h−1. The chemical oxygen demand (COD) removal efficiency reached 92.39% after 240 min of degradation under the optimized conditions and the after-treatment COD value was 379.51 mg L−1 which was lower than the centralized emission standard (less than 400 mg L−1). These findings demonstrated the feasibility and efficiency of electrocatalytically degrading coal tar wastewater by BA-PbO2 electrodes. The possible mechanism and pathway for phenol a specific pollutant in coal tar wastewater were investigated by quantum chemistry calculations (Multiwfn) and gas chromatography-mass spectrometry (GC-MS). The toxicity of each intermediate was predicted by the ECOSAR program. [Display omitted] •A novel hydrophobic PbO2 electrode was fabricated and characterized.•BA-PbO2 electrode effectively remove phenol from actual coal tar wastewater.•Degradation pathways and ecotoxicity were revealed systematically.•Fukui functions and dual descriptor were calculated to predict reactive sites.•A novel continuous cycle reactor was used in the degradation system.