Oxidative and hydrolytic stability of boron nitride — A new approach to improving the oxidation resistance of carbonaceous structures

• Published in: Carbon (New York) 1995, Vol.33 (4), p.389-395
• Main Authors: Cofer, Cameron G., Economy, James
• Format: Article
• Language: English
• Subjects: Boron nitride; carbon-carbon composites; coatings; moisture stability; oxidation resistance
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/0008-6223(94)00163-T

Boron nitride (BN), derived from borazine oligomers, was examined as a means of enhancing the oxidation resistance of carbon fiber-carbon matrix composites (CC). To clarify the widely held impression that BN suffers from a hydrolytic instability, a systematic investigation of the accelerated hydrolysis of BN at 700 °C was carried out. These results showed that the stability to moisture was directly related to the degree of crystalline perfection. A similar argument was found to hold with respect to resistance of BN toward air oxidation. Based on these data, processing conditions were designed to yield a very stable BN with an interlayer spacing of d(002) = 3.35 Å. A number of different schemes were employed to test the ability of BN to impart high-temperature oxidation stability to carbon fiber composites. These included: BN coatings on CC composites, infiltration of BN into porous CC, BN as the matrix in a carbon fiber lay-up (C-BN), and BN fiber-BN matrix composites (BN-BN). In all cases, incorporation of BN was shown to improve the oxidation resistance, with the BN-BN composite exhibiting the highest stability in air.