Mutually Noninterfering Flexible Pressure–Temperature Dual-Modal Sensors Based on Conductive Metal–Organic Framework for Electronic Skin

• Published in: ACS nano 2022-01, Vol.16 (1), p.473-484
• Main Authors: Li, Yuxiang, Wang, Ranran, Wang, Guan-E, Feng, Shiyang, Shi, Wenge, Cheng, Yin, Shi, Liangjing, Fu, Kaiyuan, Sun, Jing
• Format: Article
• Language: English
• Subjects: Electric Conductivity; Humans; Metal-Organic Frameworks; Skin - chemistry; Temperature; Wearable Electronic Devices
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.1c07388

Pressure and temperature are two important indicators for human skin perception. Electronic skin (E-skin) that mimics human skin within one single flexible sensor is beneficial for detecting and differentiating pressure and temperature and showing immunity from tensile strain disruptions. However, few studies have simultaneously realized these conditions. Herein, a flexible and strain-suppressed pressure–temperature dual-modal sensor based on conductive and microstructured metal–organic framework (MOF) films was reported and mainly prepared by in situ growing Ni3(HiTP)2 onto microstructured mixed cellulose (MSMC) substrates. The sensor exhibits distinguishable and strain-suppressed properties for pressure (sensing range up to 300 kPa, sensitivity of 61.61 kPa–1, response time of 20 ms, and ultralow detection limit of 1 Pa) and temperature sensing (sensitivity of 57.1 μV/K). Theoretical calculations successfully analyzed the mutually noninterfering mechanism between pressure and temperature. Owing to its effective perception in static and dynamic surroundings, this sensor has great potential applications, such as in electronic skin and smart prosthetics.