Response to the Temperature and Solvent Stimulation of MOF Material in a Single-Crystal to Single-Crystal Manner

Under solvothermal conditions, a three-dimensional mononuclear crystal AQNU-1, {[Co­(H2L)­(DPD)­(H2O)2]·2DMA} n (H2L = 5-(bis­(4-carboxybenzyl)­amino)­isophthalic acid, DPD = 4,4′-(2,5-diethoxy-1,4-phenylene)­dipyridine) has been synthesized. The transformations of AQNU-1 to binuclear {[Co2(L)­(DPD)...

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Published in:Inorganic chemistry 2022-01, Vol.61 (1), p.47-51
Main Authors: Qian, Jian-Lei, Zhou, Tao, Lu, Xin, Xu, Heng, Sun, Jia-Yin, Zhang, Chuan-Lei, Zheng, He-Gen
Format: Article
Language:English
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Summary:Under solvothermal conditions, a three-dimensional mononuclear crystal AQNU-1, {[Co­(H2L)­(DPD)­(H2O)2]·2DMA} n (H2L = 5-(bis­(4-carboxybenzyl)­amino)­isophthalic acid, DPD = 4,4′-(2,5-diethoxy-1,4-phenylene)­dipyridine) has been synthesized. The transformations of AQNU-1 to binuclear {[Co2(L)­(DPD)1.5(H2O)3]·DMA·H2O} n (AQNU-2) and pentanuclear {[Co5(L)2(DPD)2(OH)2]·2H2O} n (AQNU-3) were realized by double stimulation of temperature and solvent, which were accomplished by single-crystal to single-crystal (SC-SC) reaction.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.1c03615