Oxidative evolution of Z / E -diaminotetraphenylethylene

We report that / -diaminotetraphenylethylene ( / -2NH -TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution accompanying the rearrangement is...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2022-01, Vol.24 (4), p.1960-1964
Main Authors: Li, Xin, Zhuang, Yongbing, Ran, Qichao, Liu, Xiangyang
Format: Article
Language:English
Subjects:
Crystal structure
Crystals
Evolution
Isomerization
Single crystals
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Summary:We report that / -diaminotetraphenylethylene ( / -2NH -TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution accompanying the rearrangement is explained through quantum theoretical calculation.
ISSN:1463-9076
1463-9084
DOI:10.1039/d1cp05303e