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Synthesis and characterization of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s
A multistep synthetic route for the preparation of a series of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s having a varying length of the polymethylene spacer from the di- to the hexamethylene group is reported. The polymers prepared were characterized particularly for their li...
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Published in: | Polymer (Guilford) 1993, Vol.34 (14), p.3019-3024 |
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container_end_page | 3024 |
container_issue | 14 |
container_start_page | 3019 |
container_title | Polymer (Guilford) |
container_volume | 34 |
creator | Jin, Jung-II Cho, Yong-II Sohn, Byung-Hee Kang, Chung-Seock |
description | A multistep synthetic route for the preparation of a series of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s having a varying length of the polymethylene spacer from the di- to the hexamethylene group is reported. The polymers prepared were characterized particularly for their liquid crystalline properties by differential scanning calorimetry, wide-angle X-ray diffractometry and observation of their textures on a polarizing optical microscope. All the polymers, with the exception of the trimethylene polymer, formed the nematic phase in melt. They exhibited the well known odd-even effect at melting temperature as well as at isotropization temperature. |
doi_str_mv | 10.1016/0032-3861(93)90629-O |
format | article |
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The polymers prepared were characterized particularly for their liquid crystalline properties by differential scanning calorimetry, wide-angle X-ray diffractometry and observation of their textures on a polarizing optical microscope. All the polymers, with the exception of the trimethylene polymer, formed the nematic phase in melt. 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They exhibited the well known odd-even effect at melting temperature as well as at isotropization temperature.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>liquid crystalline polymers</subject><subject>main chain polyesters</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)</subject><subject>Polymers with particular structures</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp9kE1Lw0AQhhdRsFb_gYccRFowul9JNhdBil9Q6EE9L5PNhKykSdxNxfjrTVrpRfA0zMzzzsdLyDmj14yy-IZSwUOhYjZLxTylMU_D1QGZMJWIkPOUHZLJHjkmJ96_U0p5xOWEmJe-7kr01gdQ54EpwYHp0Nlv6GxTB00RtE3Vz5qvPmRXMmxLrPsKaxwKBlzWDNmfxqhYY1du87k_JUcFVB7PfuOUvD3cvy6ewuXq8XlxtwyNiGUX5piJLIMo54KzxCQxKxRjVCqhEDiTPOFApUwylgkJNI0gY6iUEhmPwHAUU3K5m9u65mODvtNr6w1WFQxXbbzmMY8SHkcDKHegcY33DgvdOrsG12tG9eioHu3So106FXrrqF4Nsovf-eANVIWD2li_10pFhxvjAbvdYTj8-mnRaW8s1gZz69B0Om_s_3t-AAy5i0Q</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>Jin, Jung-II</creator><creator>Cho, Yong-II</creator><creator>Sohn, Byung-Hee</creator><creator>Kang, Chung-Seock</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1993</creationdate><title>Synthesis and characterization of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s</title><author>Jin, Jung-II ; Cho, Yong-II ; Sohn, Byung-Hee ; Kang, Chung-Seock</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-deb3bba5d23217c761f81104838ea214272a0447b1b34a095ab1e8883b25ac2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>liquid crystalline polymers</topic><topic>main chain polyesters</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)</topic><topic>Polymers with particular structures</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jin, Jung-II</creatorcontrib><creatorcontrib>Cho, Yong-II</creatorcontrib><creatorcontrib>Sohn, Byung-Hee</creatorcontrib><creatorcontrib>Kang, Chung-Seock</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jin, Jung-II</au><au>Cho, Yong-II</au><au>Sohn, Byung-Hee</au><au>Kang, Chung-Seock</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s</atitle><jtitle>Polymer (Guilford)</jtitle><date>1993</date><risdate>1993</risdate><volume>34</volume><issue>14</issue><spage>3019</spage><epage>3024</epage><pages>3019-3024</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>A multistep synthetic route for the preparation of a series of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s having a varying length of the polymethylene spacer from the di- to the hexamethylene group is reported. 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ispartof | Polymer (Guilford), 1993, Vol.34 (14), p.3019-3024 |
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subjects | Applied sciences Exact sciences and technology liquid crystalline polymers main chain polyesters Organic polymers Physicochemistry of polymers poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene) Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts |
title | Synthesis and characterization of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s |
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