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Synthesis and characterization of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s

A multistep synthetic route for the preparation of a series of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s having a varying length of the polymethylene spacer from the di- to the hexamethylene group is reported. The polymers prepared were characterized particularly for their li...

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Published in:Polymer (Guilford) 1993, Vol.34 (14), p.3019-3024
Main Authors: Jin, Jung-II, Cho, Yong-II, Sohn, Byung-Hee, Kang, Chung-Seock
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Language:English
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container_end_page 3024
container_issue 14
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container_title Polymer (Guilford)
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creator Jin, Jung-II
Cho, Yong-II
Sohn, Byung-Hee
Kang, Chung-Seock
description A multistep synthetic route for the preparation of a series of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s having a varying length of the polymethylene spacer from the di- to the hexamethylene group is reported. The polymers prepared were characterized particularly for their liquid crystalline properties by differential scanning calorimetry, wide-angle X-ray diffractometry and observation of their textures on a polarizing optical microscope. All the polymers, with the exception of the trimethylene polymer, formed the nematic phase in melt. They exhibited the well known odd-even effect at melting temperature as well as at isotropization temperature.
doi_str_mv 10.1016/0032-3861(93)90629-O
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ispartof Polymer (Guilford), 1993, Vol.34 (14), p.3019-3024
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source Backfile Package - Materials Science [YMS]
subjects Applied sciences
Exact sciences and technology
liquid crystalline polymers
main chain polyesters
Organic polymers
Physicochemistry of polymers
poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)
Polymers with particular structures
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Synthesis and characterization of poly(oxy-1,4-phenyleneoxycarbonyl-1,4-phenyleneoxypolymethylene)s
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