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The double network, a model describing filled elastomers
The model presented here to describe the deformation behaviour of filled elastomers is based on the observation that deformation occurs inhomogeneously. As a result of extending a filled rubber, the filler particles become aligned in rows parallel to the stretching direction. The rows are connected...
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Published in: | Polymer (Guilford) 1993, Vol.34 (6), p.1216-1221 |
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cited_by | cdi_FETCH-LOGICAL-c430t-2b3248116c1823c26a0325e6d8cb435ca6f192349ce818b6f1bc173a480412083 |
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cites | cdi_FETCH-LOGICAL-c430t-2b3248116c1823c26a0325e6d8cb435ca6f192349ce818b6f1bc173a480412083 |
container_end_page | 1221 |
container_issue | 6 |
container_start_page | 1216 |
container_title | Polymer (Guilford) |
container_volume | 34 |
creator | Reichert, Werner Franz Göritz, Dietmar Duschl, Edgar Johannes |
description | The model presented here to describe the deformation behaviour of filled elastomers is based on the observation that deformation occurs inhomogeneously. As a result of extending a filled rubber, the filler particles become aligned in rows parallel to the stretching direction. The rows are connected to each other by strands emanating from the filler particles, forming a second network that is superimposed on the molecular network. The stress-strain behaviour can be described by writing the stress as a superposition of stresses of the individual networks,
σ = (1 −
Φ)
σ
1 +
Φσ
2. The parameter Ф gives the volume fraction of strands between the filler particles. Macroscopic properties such as stress-strain behaviour or stress-induced crystallization of filled elastomers are described well by this model. |
doi_str_mv | 10.1016/0032-3861(93)90776-7 |
format | article |
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σ = (1 −
Φ)
σ
1 +
Φσ
2. The parameter Ф gives the volume fraction of strands between the filler particles. Macroscopic properties such as stress-strain behaviour or stress-induced crystallization of filled elastomers are described well by this model.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/0032-3861(93)90776-7</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; elastomers ; Exact sciences and technology ; filler ; fully extended chains ; Mechanical properties ; network model ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; reinforcement ; stress-induced crystallization ; stress-strain behaviour</subject><ispartof>Polymer (Guilford), 1993, Vol.34 (6), p.1216-1221</ispartof><rights>1993</rights><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-2b3248116c1823c26a0325e6d8cb435ca6f192349ce818b6f1bc173a480412083</citedby><cites>FETCH-LOGICAL-c430t-2b3248116c1823c26a0325e6d8cb435ca6f192349ce818b6f1bc173a480412083</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/0032386193907767$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3555,4024,27923,27924,27925,46004</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4639111$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Reichert, Werner Franz</creatorcontrib><creatorcontrib>Göritz, Dietmar</creatorcontrib><creatorcontrib>Duschl, Edgar Johannes</creatorcontrib><title>The double network, a model describing filled elastomers</title><title>Polymer (Guilford)</title><description>The model presented here to describe the deformation behaviour of filled elastomers is based on the observation that deformation occurs inhomogeneously. As a result of extending a filled rubber, the filler particles become aligned in rows parallel to the stretching direction. The rows are connected to each other by strands emanating from the filler particles, forming a second network that is superimposed on the molecular network. The stress-strain behaviour can be described by writing the stress as a superposition of stresses of the individual networks,
σ = (1 −
Φ)
σ
1 +
Φσ
2. The parameter Ф gives the volume fraction of strands between the filler particles. Macroscopic properties such as stress-strain behaviour or stress-induced crystallization of filled elastomers are described well by this model.</description><subject>Applied sciences</subject><subject>elastomers</subject><subject>Exact sciences and technology</subject><subject>filler</subject><subject>fully extended chains</subject><subject>Mechanical properties</subject><subject>network model</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>reinforcement</subject><subject>stress-induced crystallization</subject><subject>stress-strain behaviour</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-Aw89iChYzSRpmlwEWfyCBS_rOaTpVKNpuyZdxX9v1108ehoGnnc-HkKOgV4CBXlFKWc5VxLOND_XtCxlXu6QCaiS54xp2CWTP2SfHKT0RillBRMTohavmNX9qgqYdTh89fH9IrNZ29cYshqTi77y3UvW-BCwzjDYNPQtxnRI9hobEh5t65Q8390uZg_5_On-cXYzz53gdMhZxZlQANKBYtwxacdDCpS1cpXghbOyAc240A4VqGrsKgclt0JRAYwqPiWnm7nL2H-sMA2m9clhCLbDfpUMk6xQGvQIig3oYp9SxMYso29t_DZAzVqTWTswawdGc_OryZRj7GQ73yZnQxNt53z6ywrJNQCM2PUGw_HXT4_RJOexc1j7iG4wde__3_MDlid5HA</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>Reichert, Werner Franz</creator><creator>Göritz, Dietmar</creator><creator>Duschl, Edgar Johannes</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1993</creationdate><title>The double network, a model describing filled elastomers</title><author>Reichert, Werner Franz ; Göritz, Dietmar ; Duschl, Edgar Johannes</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-2b3248116c1823c26a0325e6d8cb435ca6f192349ce818b6f1bc173a480412083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Applied sciences</topic><topic>elastomers</topic><topic>Exact sciences and technology</topic><topic>filler</topic><topic>fully extended chains</topic><topic>Mechanical properties</topic><topic>network model</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>reinforcement</topic><topic>stress-induced crystallization</topic><topic>stress-strain behaviour</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reichert, Werner Franz</creatorcontrib><creatorcontrib>Göritz, Dietmar</creatorcontrib><creatorcontrib>Duschl, Edgar Johannes</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reichert, Werner Franz</au><au>Göritz, Dietmar</au><au>Duschl, Edgar Johannes</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The double network, a model describing filled elastomers</atitle><jtitle>Polymer (Guilford)</jtitle><date>1993</date><risdate>1993</risdate><volume>34</volume><issue>6</issue><spage>1216</spage><epage>1221</epage><pages>1216-1221</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>The model presented here to describe the deformation behaviour of filled elastomers is based on the observation that deformation occurs inhomogeneously. As a result of extending a filled rubber, the filler particles become aligned in rows parallel to the stretching direction. The rows are connected to each other by strands emanating from the filler particles, forming a second network that is superimposed on the molecular network. The stress-strain behaviour can be described by writing the stress as a superposition of stresses of the individual networks,
σ = (1 −
Φ)
σ
1 +
Φσ
2. The parameter Ф gives the volume fraction of strands between the filler particles. Macroscopic properties such as stress-strain behaviour or stress-induced crystallization of filled elastomers are described well by this model.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/0032-3861(93)90776-7</doi><tpages>6</tpages></addata></record> |
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ispartof | Polymer (Guilford), 1993, Vol.34 (6), p.1216-1221 |
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language | eng |
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source | ScienceDirect: Materials Science Backfile |
subjects | Applied sciences elastomers Exact sciences and technology filler fully extended chains Mechanical properties network model Organic polymers Physicochemistry of polymers Properties and characterization reinforcement stress-induced crystallization stress-strain behaviour |
title | The double network, a model describing filled elastomers |
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