Ultrathin covalent and cuprophilic interaction-assembled copper-sulfur monolayer in organic metal chalcogenide for oriented photoconductivity

We report the thinnest copper sulfur atomic monolayer in an organic copper chalcogenide [Cu(CMP)] (CMP = 5-chloro-2-mercaptopyridine). The layer features a new type of copper sulfur structure woven by both covalent bond and cuprophilic interaction and shows an intriguing oriented photoconductivity.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2022-02, Vol.58 (17), p.2858-2861
Main Authors: Liu, Guang-Ning, Xu, Rang-Dong, Li, Ming-Kun, Sun, Yiqiang, Zhou, Meng-Jie, Cai, Rui-Yun, You, Zuo-Jiang, Jiang, Xiao-Ming, Li, Cuncheng
Format: Article
Language:English
Subjects:
Chalcogenides
Copper
Covalent bonds
Monolayers
Photoconductivity
Sulfur
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Summary:We report the thinnest copper sulfur atomic monolayer in an organic copper chalcogenide [Cu(CMP)] (CMP = 5-chloro-2-mercaptopyridine). The layer features a new type of copper sulfur structure woven by both covalent bond and cuprophilic interaction and shows an intriguing oriented photoconductivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00145d