Omnibearing Interpretation of External Ions Passivated Ion Migration in Mixed Halide Perovskites

• Published in: Nano letters 2022-02, Vol.22 (4), p.1467-1474
• Main Authors: Wu, Hualin, Xu, Chenzhe, Zhang, Zihan, Xiong, Zhaozhao, Shi, Mingyue, Ma, Shuangfei, Fan, Wenqiang, Zhang, Zheng, Liao, Qingliang, Kang, Zhuo, Zhang, Yue
• Format: Article
• Language: English
• ISSN: 1530-6984; 1530-6992
• DOI: 10.1021/acs.nanolett.1c03336

Fundamental understanding of ion migration inside perovskites is of vital importance for commercial advancements of photovoltaics. However, the mechanism for external ions incorporation and its effect on ion migration remains elusive. Herein, taking K+ and Cs+ co-incorporated mixed halide perovskites as a model, the impact of external ions on ion migration behavior has been interpreted via multiple dimensional characterization aspects. The space-effect on phase segregation inhibition has been revealed by the photoluminescence evolution and in situ dynamic cathodoluminescence behaviors. The plane-effect on current suppression along grain boundary has been evidenced via visualized surface current mapping, local current hysteresis, and time-resolved current decay. And the point-effect on activation energy incremental for individual ions has been also probed by cryogenic electronic quantification. All these results sufficiently demonstrate the passivated ion migration results in the eventually improved phase stability of perovskite, of which the origin lies in various ion migration energy barriers.