A Practically Unified Electrochemical Strategy for Ni-Catalyzed Decarboxylative Cross-Coupling of Aryl Trimethylammonium Salts

By merging electrocatalysis and nickel catalysis, a unified strategy has been successfully applied to achieve the decarboxylative cross-coupling of four types of α-oxocarboxylic acids and their derivatives with aryl trimethylammonium salts under mild conditions. Our strategy provides a practical way...

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Bibliographic Details
Published in:Organic letters 2022-03, Vol.24 (11), p.2137-2142
Main Authors: Kong, Xianqiang, Chen, Yiyi, Chen, Xiaohui, Lu, Zheng-Xuan, Wang, Wei, Ni, Shao-Fei, Cao, Zhong-Yan
Format: Article
Language:English
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Summary:By merging electrocatalysis and nickel catalysis, a unified strategy has been successfully applied to achieve the decarboxylative cross-coupling of four types of α-oxocarboxylic acids and their derivatives with aryl trimethylammonium salts under mild conditions. Our strategy provides a practical way for preparing aryl ketones, amides, esters, or aldehydes.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.2c00408