The foam film's stepwise thinning phenomenon and role of oscillatory forces

• Published in: Advances in colloid and interface science 2022-05, Vol.303, p.102636-102636, Article 102636
• Main Authors: Nikolov, Alex D., Wasan, Darsh T.
• Format: Article
• Language: English
• Subjects: area; Curved; Foam. micellar, film; Modeling; RDF; Stepwise thinning
• ISSN: 0001-8686; 1873-3727
• DOI: 10.1016/j.cis.2022.102636

As a foam film formed from complex fluids thins, the particles under the film confinement self-organize into layers. Reflected light was used to monitor the rate of layer-by-layer thinning and the layers' thickness. The microscopic and macroscopic films thin using the same stepwise manner (stratify), via layers or stripes with equal thicknesses. The roles of the film area (size) and film capillary pressure on the film stepwise thinning were studied. A micron-sized dot with a thickness one layer less than that of the surrounding film area is observed. The dot expands into a spot when the film reaches the critical area. The 2D dot-spot exhibits a threshold process. The spot expands and the film's stepwise thinning begins. When the film area is reduced, the spot stops expanding and begins to reduce in size. The film slowly recovers its original thickness in a stepwise manner, one layer at a time. It was demonstrated that the film area is the governing factor in the film stepwise thinning rather than the film capillary pressure. A particle dislocation-diffusion-osmotic pressure model is proposed to explain the mechanism of the film stepwise thinning phenomenon via dot-spot formation. The model explains all the features of the foam stepwise thinning phenomenon, including the reversibility of the film's stepwise thinning. For the first time for a film with a thickness less than three layers, a 2D in-layer hexagonal particle entropy structural transition was observed and theoretically predicted by the analysis of the Radial Distribution Function (RDF). [Display omitted] •TConfinement, Layer, In -Layer, Entropy, Strutural , Transition , RDF.•Dislocation, Model Stepwise, Phenomenon, Reversability.