Ce(III)/Photoassisted Synthesis of Amides from Carboxylic Acids and Isocyanates

The Ce­(III)-photocatalyzed synthesis of amides from carboxylic acids and aryl isocyanates was developed. The reaction includes the formation of alkyl radicals from carboxylic acids followed by radical addition to the electron-deficient carbon of isocyanate.

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Bibliographic Details
Published in:Organic letters 2022-04, Vol.24 (12), p.2431-2435
Main Authors: Li, Hao-Cong, Li, Guan-Nan, Sun, Kai, Chen, Xiao-Lan, Jiang, Ming-Xuan, Qu, Ling-Bo, Yu, Bing
Format: Article
Language:English
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Summary:The Ce­(III)-photocatalyzed synthesis of amides from carboxylic acids and aryl isocyanates was developed. The reaction includes the formation of alkyl radicals from carboxylic acids followed by radical addition to the electron-deficient carbon of isocyanate.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.2c00699