Solvent Effects on the Photophysical Properties of a Donor–acceptor Based Schiff Base

• Published in: Journal of fluorescence 2022-07, Vol.32 (4), p.1321-1336
• Main Authors: Nath, Surjatapa, Bhattacharya, Barnali, Sarkar, Utpal, Singh, T. Sanjoy
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Biochemistry; Biological and Medical Physics; Biomedical and Life Sciences; Biomedicine; Biophysics; Biotechnology; Charge distribution; Charge transfer; Density functional theory; Dipole moments; Electron density; Electron states; Excitation; Fluorescence; Imines; Mathematical analysis; Molecular orbitals; Original Article; Pictures; Quantum chemistry; Solvent effect; Solvents; Spectrum analysis; Steady state
• ISSN: 1053-0509; 1573-4994
• DOI: 10.1007/s10895-022-02905-6

In this work, a donor–acceptor substituted aromatic system ((E)-N-((E)-3-(4 (dimethylamino)phenyl) allylidene)-4-(trifluoromethyl) benzenamine (DPATB) has been synthesized and its detailed photophysics of intramolecular charge transfer process have been explored on the basis of steady state absorption, fluorescence and time resolved spectroscopy in combination with density functional theory calculations. Large solvent dependency fluorescence spectral shift and the calculated large excited state dipole moment clearly indicate an efficient charge transfer occurring from the donor group to the acceptor moiety in the excited state. Effect on addition of acid and pH on steady state spectral properties further reveals excited state charge transfer character. Quantum chemical calculations were performed in order to study the conformation and polarity of DPATB at their ground as well as excited electronic states. The HOMO and LUMO molecular orbital pictures are obtained at DFT level using B3LYP functional and 6–311 + g(d,p) basis set which clearly support excited state intramolecular charge transfer process. The molecular electrostatic potential maps for the optimized ground state, donor twisted and acceptor twisted geometry shed insight on the electrostatic potential and charge distribution in a system which gives information about the reacting site of the probe and nature of the reaction. Graphical abstract In this work, detailed photophysics of excited state intramolecular charge transfer process in donor–acceptor system (DPATB) was evaluated using steady state and time-resolved fluorescence spectroscopy in combination with density functional theory calculations. Large solvent dependency fluorescence spectral shift and the calculated large excited state dipole moment clearly indicate an efficient charge transfer occurring in DPATB. Molecular orbital pictures as obtained from DFT based computational analysis reveals a significant change in the distribution of electron density upon transition from HOMO to LUMO which confirms an ICT process occurring from the donor group to the acceptor moiety in the excited state.