Mechanistic Underpinnings of Morphology Transition in Electrodeposition under the Application of Pulsatile Potential

• Published in: Langmuir 2022-04, Vol.38 (16), p.4879-4886
• Main Authors: Dhara, Trina, Ghosh, Udita Uday, Ghosh, Asmita, Vishnugopi, Bairav Sabarish, Mukherjee, Partha P, DasGupta, Sunando
• Format: Article
• Language: English
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.2c00066

We quantitatively investigate the role of voltage fluctuation in terms of different waveforms on the electrodeposition dynamics and morphology for varying electrolyte concentrations. Dependent on the electrolyte concentration, a wide range of morphologies ranging from highly branched dendrites to comparatively closed packed electrodeposits has been captured. We mechanistically map the deposition dynamics by image analysis and demonstrate the highly porous dendritic dynamics to be independent of external perturbation. Additionally, comparatively closed packed morphological features show significant sensitivity toward the frequency and nature of the waveforms. The results provide fundamental insights into the correlation between the time scales of voltage fluctuation and growth dynamics. We comprehensively analyze the effect of the waveform nature on the average deposition height and show sinusoidal fluctuation to be preferred over square and pulse for metal batteries for lower deposition heights.