Cathodic reduction of 2-bromo-2-nitropropane in the presence of dipolarophiles

Cathodic reduction of 2-bromo-nitropropane in aprotic medium in the presence of dimethyl acetylene dicarboxylate led to 5,5-dimethyl-2,3,4-trimethoxycarbonyl-5-hydropyrrole and dimethyl 2-(1-nitroisopropyl)-2-butenedioate. In the presence of methyl propiolate a mixture of 2-nitropropane, 2,3-dimethy...

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Bibliographic Details
Published in:Electrochimica acta 1997, Vol.42 (13), p.2177-2180
Main Authors: Montero, Guillermo, Quintanilla, Gloria, Barba, Fructuoso
Format: Article
Language:English
Subjects:
2-bromo-2-nitropropane
Cathodic reduction
dimethylacetylene dicarboxilate
methyl propiolate
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Summary:Cathodic reduction of 2-bromo-nitropropane in aprotic medium in the presence of dimethyl acetylene dicarboxylate led to 5,5-dimethyl-2,3,4-trimethoxycarbonyl-5-hydropyrrole and dimethyl 2-(1-nitroisopropyl)-2-butenedioate. In the presence of methyl propiolate a mixture of 2-nitropropane, 2,3-dimethyl-2,3-dinitrobutane, methyl (E)-4-methyl-4-nitro-2-pentenoate and an organomercurial compound was obtained.
ISSN:0013-4686
1873-3859
DOI:10.1016/S0013-4686(97)85496-5