DeNO x performance enhancement of Cu-based oxides via employing a TiO2 phase to modify LDH precursors

• Published in: RSC advances 2022-03, Vol.12 (16), p.10142
• Main Authors: Du, Yali, Liu, Xuezhen, Liu, Jiangning, Du, Rongting, Wu, Xu
• Format: Article
• Language: English
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d2ra00316c

CuAl-LDO, CuAl-LDO/TiO2 and CuAl-LDO/TiO2NTs catalysts were obtained from TiO2 modified LDHs precursor which were prepared by in situ assembly method. Then catalysts were evaluated in the selective catalytic reduction of NO x with NH3(NH3-SCR), and the results showed that the CuAl-LDO/TiO2NTs catalyst exhibited preferable deNO x performance (more than 80% NO x conversion and higher than 90% N2 selectivity at a temperature range of 210-330 °C) as well as good SO2 resistance. With the aid of series of characterizations such as XRD, N2 adsorption/desorption, XPS, NH3-TPD, H2-TPR, and in situ DRIFTS, it could be concluded that, doping TiO2NTs afforded the catalyst larger specific surface area, more abundant surface chemisorption oxygen species and more excellent redox performance. Meanwhile, In situ DRIFTS evidenced that CuAl-LDO/TiO2NTs catalyst has a strong adsorption capacity for the reaction gas, which is more conducive to the progress of the SCR reaction.CuAl-LDO, CuAl-LDO/TiO2 and CuAl-LDO/TiO2NTs catalysts were obtained from TiO2 modified LDHs precursor which were prepared by in situ assembly method. Then catalysts were evaluated in the selective catalytic reduction of NO x with NH3(NH3-SCR), and the results showed that the CuAl-LDO/TiO2NTs catalyst exhibited preferable deNO x performance (more than 80% NO x conversion and higher than 90% N2 selectivity at a temperature range of 210-330 °C) as well as good SO2 resistance. With the aid of series of characterizations such as XRD, N2 adsorption/desorption, XPS, NH3-TPD, H2-TPR, and in situ DRIFTS, it could be concluded that, doping TiO2NTs afforded the catalyst larger specific surface area, more abundant surface chemisorption oxygen species and more excellent redox performance. Meanwhile, In situ DRIFTS evidenced that CuAl-LDO/TiO2NTs catalyst has a strong adsorption capacity for the reaction gas, which is more conducive to the progress of the SCR reaction.