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Visible-light-induced cyclization of cyclic N -sulfonyl ketimines to N -sulfonamide fused imidazolidines

A visible-light-induced metal-free cascade cyclization of cyclic -sulfonyl ketimines with -arylglycines for the construction of -sulfonamide-fused imidazolidines was developed. The procedure employed 3 mol% of eosin Y as the photocatalyst at room temperature under visible light irradiation, providin...

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Published in:Organic & biomolecular chemistry 2022-05, Vol.20 (18), p.3798-3802
Main Authors: Wang, Xiaotong, Shi, Anzai, Huang, Xian-Qiang, Chen, Xiaolan, Li, Tiesheng, Qu, Lingbo, Yu, Bing
Format: Article
Language:English
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Summary:A visible-light-induced metal-free cascade cyclization of cyclic -sulfonyl ketimines with -arylglycines for the construction of -sulfonamide-fused imidazolidines was developed. The procedure employed 3 mol% of eosin Y as the photocatalyst at room temperature under visible light irradiation, providing various -sulfonamide-fused imidazolidines in good yields (32 examples, up to 86% yields).
ISSN:1477-0520
1477-0539
DOI:10.1039/d2ob00460g